4,5'-bis(N-carbazolyl)-2'-phenylpyrimidine | 1384055-92-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 4,5'-bis(N-carbazolyl)-2'-phenylpyrimidine
• 英文别名: 9-[2-(4-Carbazol-9-ylphenyl)pyrimidin-5-yl]carbazole
• CAS: 1384055-92-8
• 化学式: C₃₄H₂₂N₄
• 分子量: 486.575
• InChiKey: JULWKOZXCYBTNM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8
• 重原子数：
  38
• 可旋转键数：
  3
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  35.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  4-溴苯硼酸 在 四(三苯基膦)钯 、 18-冠醚-6 、 铜 、 potassium carbonate 作用下， 以 四氢呋喃 、 水 、 邻二氯苯 为溶剂， 反应 184.0h， 生成 4,5'-bis(N-carbazolyl)-2'-phenylpyrimidine
  参考文献：
  名称：

  用于高效单层磷光OLED的基于N杂环咔唑的主体

  摘要：

  使用新型的基于N-杂环咔唑的主体材料展示了高效的单层有机发光二极管（OLED）。制备了具有ITO / MoO 3 /主体/主体：掺杂剂/主体/ Cs 2 CO 3 / Al结构的磷光OLED，其中新材料同时充当电子传输，空穴传输和主体层。实现了最大电流和外部量子效率分别为92.2 cd A -1和26.8％的器件，这是迄今为止单层OLED所报道的最高值。

  DOI：

  10.1002/adma.201200927

文献信息

• METAL-COMPLEX COMPOUND AND ORGANIC ELECTROLUMINESCENCE DEVICE USING THE COMPOUND
  申请人：WATANABE Masami

  公开号：US20070108891A1

  公开（公告）日：2007-05-17

  A metal complex compound having a specific structure having a metal such as iridium, and an organic electroluminescence device which has an organic thin film layer having one layer or a plurality of layers including at least a light emitting layer and disposed between a pair of electrodes and contains the metal complex in at least one layer in the organic thin film layer. The organic electroluminescence device exhibits a great efficiency of light emission and has a long life due to the metal complex compound.

  一种具有特定结构的金属络合物化合物，其中金属例如铱，并且具有包括至少一个发光层的一个层或多个层的有机薄膜层，位于一对电极之间并在有机薄膜层中的至少一层中含有金属络合物的有机电致发光器件。由于金属络合物化合物，这种有机电致发光器件表现出很高的发光效率并且具有长寿命。
• Blue organic electroluminescent device
  申请人：Matsuura Masahide

  公开号：US20070069638A1

  公开（公告）日：2007-03-29

  A blue organic electroluminescent device ( 1 ) including at least an emitting layer ( 40 ) between an anode ( 20 ) and a cathode ( 60 ), the emitting layer ( 40 ) including a host material and a plurality of dopants, at least one of the dopants having ultraviolet luminescent properties.
• Metal complex compound and organic electroluminescence device containing the same
  申请人：Okuda Fumino

  公开号：US20070111024A1

  公开（公告）日：2007-05-17

  A metal-complex compound having a special structure containing metals such as iridium. An organic electroluminescence device which comprises at least one organic thin film layer sandwiched between a pair of electrode consisting of an anode and a cathode, wherein the organic thin film layer comprises the metal-complex compound, which emits light by applying an electric voltage between the pair of electrode. An organic EL device employing the novel metal-complex compound emits various phosphorous light including blue light having an enhanced current efficiency and prolonged lifetime.
• TRANSITION METAL COMPLEX COMPOUND AND ORGANIC ELECTROLUMINESCENCE DEVICE USING THE COMPOUND
  申请人：Watanabe Masami

  公开号：US20070141397A1

  公开（公告）日：2007-06-21

  The present invention relates to a transition metal complex compound of a specific structure having a metal carbene bond and an organic electroluminescent device in which an organic thin film layer comprising a single layer or plural layers having at least a light emitting layer is interposed between an anode and a cathode, wherein at least one layer in the organic thin film layer contains the transition metal complex compound described above, and provided are an organic EL device having a high luminous efficiency and emitting blue light and a transition metal complex compound materializing the same.
• Transition metal complex compound and organic electroluminescence device using the compound
  申请人：Watanabe Masami

  公开号：US20070176540A1

  公开（公告）日：2007-08-02

  Provided are an organic electroluminescence device having high luminous efficiency and a long emission lifetime, and a transition metal complex compound realizing the organic electroluminescence device. In the transition metal complex compound, three ligands are crosslinked with a crosslinking group having a saturated cyclic structure or a saturated polycyclic structure in a tripod manner. The organic electroluminescence device includes an organic thin film layer composed of one or multiple layers including at least a light emitting layer, the organic thin film layer being interposed between a pair of electrodes. In the organic electroluminescence device, at least one layer of the organic thin film layer contains the transition metal complex compound.