(bis(3,5-dimethylpyrazolyl)dimethylsilane)ZnI2 | 308097-14-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: (bis(3,5-dimethylpyrazolyl)dimethylsilane)ZnI2
• 英文别名: bis(3,5-dimethylpyrazol-1-yl)-dimethylsilane;diiodozinc
• CAS: 308097-14-5
• 化学式: C₁₂H₂₀I₂N₄SiZn
• 分子量: 567.602
• InChiKey: GKBCEBGYHKVDOG-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1-[(3,5-dimethyl-1-pyrazol-1-yl)dimethylsilyl]-3,5-dimethyl-1Н-pyrazole 、 zinc(II) iodide 以 乙醚 为溶剂， 以85%的产率得到(bis(3,5-dimethylpyrazolyl)dimethylsilane)ZnI2
  参考文献：
  名称：

  Zinc bis(pyrazolyl)silane complexes

  摘要：

  The first two members of a new family of nitrogen-donor ligands, the bis(pyrazolyl)silanes Me2Si(3,5-R(2)pz)(2) (R = I-I, Me), have been readily synthesized in almost quantitative yield from Me2SiCl2 and the alkali metal pyrazolates M(3,5-R(2)pz) (M = Li or Na). Both bidentate ligands, abbreviated Bps and Bps(Me2), respectively, have been used to prepare the zinc derivatives LZnX2 (L = Bps, Bps(Me2); X = Cl, Br, I), all of which have been characterized by a combination of analytical and spectroscopic techniques and, in the case of (Bps(Me2))ZnI2, also by single-crystal X-ray diffraction. (C) 2000 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(00)00470-8