β-Chlor-α-methylmercapto-acrylsaeuremethylester | 5247-34-7

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 英文名称: β-Chlor-α-methylmercapto-acrylsaeuremethylester
• 英文别名: Methyl 3-chloro-2-(methylsulfanyl)prop-2-enoate；methyl 3-chloro-2-methylsulfanylprop-2-enoate
• CAS: 5247-34-7
• 化学式: C₅H₇ClO₂S
• 分子量: 166.628
• InChiKey: DJUUAFGRCUXEDJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  9
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  51.6
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  在 氯化亚砜 作用下， 生成 β-Chlor-α-methylmercapto-acrylsaeuremethylester
  参考文献：
  名称：

  Winterfeldt,E.; Dillinger,H.-J., Chemische Berichte, 1966, vol. 99, p. 1558 - 1568

  摘要：

  DOI：

文献信息

• ALPHA, BETA-UNSATURATED IMIDATE COMPOUND AND PESTICIDAL COMPOSITION CONTAINING THE SAME
  申请人：Itoh Shigeyuki

  公开号：US20100240729A1

  公开（公告）日：2010-09-23

  There is provided a compound having an excellent controlling effect on pests, represented by the formula (I): wherein, A and E independently represent a —R 1 group, a -L 1 -R 1 group, etc.; G represents a -L 2 -R 1 group, a —S(O) 2 —R 4 group, etc.; X represents a —S—R 5 group or a —O—R 6 group; Z represents an optionally substituted carbocyclic group or an optionally substituted heterocyclic group; R 1 represents an optionally substituted C1-C20 chain hydrocarbon group, etc.; R 5 represents a substituted C1-C4 alkyl group, an optionally substituted C5-C10 alkyl group, etc.; R 6 represents a substituted C1-C2 alkyl group, an optionally substituted C3-C10 alkyl group, etc.; L 1 represents a an oxygen atom, a sulfur atom, a —S(O)— group, or a —S(O) 2 -group; and L 2 represents an oxygen atom or a sulfur atom.

  提供一种具有优异的害虫控制效果的化合物，其化学式表示为（I）：其中，A和E独立地表示—R1基团、-L1-R1基团等；G表示-L2-R1基团、—S（O）2—R4基团等；X表示—S—R5基团或—O—R6基团；Z表示可选取代的碳环基团或可选取代的杂环基团；R1表示可选取代的C1-C20链烃基团等；R5表示取代的C1-C4烷基团、可选取代的C5-C10烷基团等；R6表示取代的C1-C2烷基团、可选取代的C3-C10烷基团等；L1表示氧原子、硫原子、—S（O）—基团或—S（O）2—基团；L2表示氧原子或硫原子。
• Alpha, beta-unsaturated imidate compound and pesticidal composition containing the same
  申请人：Sumitomo Chemical Company, Limited

  公开号：US08278473B2

  公开（公告）日：2012-10-02

  There is provided a compound having an excellent controlling effect on pests, represented by the formula (I): wherein, A and E independently represent a —R1 group, a -L1-R1 group, etc.; G represents a -L2-R1 group, a —S(O)2—R4 group, etc.; X represents a —S—R5 group or a —O—R6 group; Z represents an optionally substituted carbocyclic group or an optionally substituted heterocyclic group; R1 represents an optionally substituted C1-C20 chain hydrocarbon group, etc.; R5 represents a substituted C1-C4 alkyl group, an optionally substituted C5-C10 alkyl group, etc.; R6 represents a substituted C1-C2 alkyl group, an optionally substituted C3-C10 alkyl group, etc.; L1 represents a an oxygen atom, a sulfur atom, a —S(O)— group, or a —S(O)2— group; and L2 represents an oxygen atom or a sulfur atom.

  提供一种具有优异的害虫控制效果的化合物，其化学式为(I)：其中，A和E分别表示-R1基团、-L1-R1基团等；G表示-L2-R1基团、-S(O)2-R4基团等；X表示-S-R5基团或-O-R6基团；Z表示可选取代的碳环基团或可选取代的杂环基团；R1表示可选取代的C1-C20链烃基团等；R5表示取代的C1-C4烷基团、可选取代的C5-C10烷基团等；R6表示取代的C1-C2烷基团、可选取代的C3-C10烷基团等；L1表示氧原子、硫原子、-S(O)基团或-S(O)2基团；L2表示氧原子或硫原子。
• Winterfeldt,E.; Dillinger,H.-J., Chemische Berichte, 1966, vol. 99, p. 1558 - 1568
  作者：Winterfeldt,E.、Dillinger,H.-J.

  DOI：——

  日期：——