| 1332462-54-0

• 分子结构分类: 有机化合物 - 有机杂环化合物
• CAS: 1332462-54-0
• 化学式: C₁₉H₂₂N₄O₄S₂
• 分子量: 434.54
• InChiKey: BIPROGSDYNOXTG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.19
• 重原子数：
  29.0
• 可旋转键数：
  9.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.53
• 拓扑面积：
  127.19
• 氢给体数：
  1.0
• 氢受体数：
  8.0

反应信息

• 作为反应物：
  描述：

  、 1,2,3,3a,4,8b-hexahydro-4-[4-(2,2-diphenylethenyl)phenyl]cyclopenta[b]indole-7-carboxaldehyde 在 ammonium acetate 、 溶剂黄146 作用下， 反应 2.0h， 以33%的产率得到DN319
  参考文献：
  名称：

  Highly efficient new indoline dye having strong electron-withdrawing group for zinc oxide dye-sensitized solar cell

  摘要：

  New indoline dye (DN319) having strong electron-withdrawing dicyanovinylidene moiety and octyl group in the terminal rhodanine ring gave higher efficiency than D205, which was known as an excellent organic dye sensitizer. This result is attributed to the bathochromic shift in the UV-vis absorption band and positive shift in the E-ox level of DN319. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2011.06.016
• 作为产物：
  描述：

  2-(3-octyl-4-oxothiazolidin-2-ylidene)malononitrile 在 盐酸 、 溶剂黄146 、 1,8-二氮杂双环[5.4.0]十一碳-7-烯 作用下， 以 水 、 乙腈 为溶剂， 反应 6.5h， 生成
  参考文献：
  名称：

  Highly efficient new indoline dye having strong electron-withdrawing group for zinc oxide dye-sensitized solar cell

  摘要：

  New indoline dye (DN319) having strong electron-withdrawing dicyanovinylidene moiety and octyl group in the terminal rhodanine ring gave higher efficiency than D205, which was known as an excellent organic dye sensitizer. This result is attributed to the bathochromic shift in the UV-vis absorption band and positive shift in the E-ox level of DN319. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2011.06.016

文献信息

• Novel indoline dye tetrabutylammonium carboxylates attached with a methyl group on the cyclopentane ring for dye-sensitized solar cells
  作者：Masaki Matsui、Yuya Tsuzuki、Yasuhiro Kubota、Kazumasa Funabiki、Toshiyasu Inuzuka、Kazuhiro Manseki、Shinji Higashijima、Hidetoshi Miura、Hiroyasu Sato、Tsukasa Yoshida

  DOI：10.1016/j.tet.2018.08.006

  日期：2018.10

  (2R,3aR,8bR)- and (2S,3aS,8bS)-2-Methyl indoline dye tetrabutylammonium carboxylates exhibited the highest conversion efficiency among four regio and stereo isomers. These indoline dyes also showed higher conversion efficiency than DN350.

  （2 R，3a R，8b R）-和（2 S，3a S，8b S）-2-甲基吲哚染料四丁基铵羧酸盐在四种区域和立体异构体中表现出最高的转化效率。这些吲哚染料的转化率也比DN350高。
• Application of novel N-(p-phenylene)-dicyanovinylidene double rhodanine indoline dye for zinc oxide dye-sensitized solar cell
  作者：Masaki Matsui、Takuo Inoue、Masaomi Ono、Yasuhiro Kubota、Kazumasa Funabiki、Jiye Jin、Tsukasa Yoshida、Shinji Higashijima、Hidetoshi Miura

  DOI：10.1016/j.dyepig.2012.08.023

  日期：2013.2

  A new indoline dye in which a double rhodanine acceptor is attached to the indoline moiety by a p-phenylene spacer on the indoline-nitrogen, has been examined for its performance as a sensitizer for zinc oxide dye-sensitized solar cells. In the presence of cholic acid, chenodeoxycholic acid, or lithocholic acid: the performance was greatest for lithocholic acid as this showed the greatest reduction in dye H-aggregate formation. (C) 2012 Elsevier Ltd. All rights reserved.