2-methyl-9-(4-biphenyl)-10-bromoanthracene | 1262749-67-6

• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物 - 芳基萘木脂素
• 英文名称: 2-methyl-9-(4-biphenyl)-10-bromoanthracene
• CAS: 1262749-67-6
• 化学式: C₂₇H₁₉Br
• 分子量: 423.352
• InChiKey: JYQGYEJJCAHQGY-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  2-methyl-9-(4-biphenyl)-10-bromoanthracene 、 2-萘硼酸 在 四(三苯基膦)钯 、 potassium carbonate 作用下， 以 四氢呋喃 为溶剂， 反应 12.0h， 以92.2%的产率得到2-methyl-9-(4-biphenyl)-10-(2-naphthyl)anthracene
  参考文献：
  名称：

  Unsymmetrically amorphous 9,10-disubstituted anthracene derivatives for high-efficiency blue organic electroluminescence devices

  摘要：

  Two unsymmetrically amorphous 9,10-disubstituted anthracene derivatives have been synthesized and characterized. They emit the light in the blue region and possess glass transition temperature of 132.5 degrees C and 133.8 degrees C. The scanning electron microscope (SEM) was employed in studying the thin-film morphological stability of the two unsymmetrical isomers. These two compounds were fabricated into typical trilayers devices with pure blue lighting performance. In addition, a series of highly efficient and stable sky blue devices doped with a sky blue dopant BUBD-1 have been fabricated by using these two isomers as the host. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2010.10.007
• 作为产物：
  描述：

  2-methyl-9-(4-biphenyl)anthracene 在 N-溴代丁二酰亚胺(NBS) 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 10.0h， 以85.4%的产率得到2-methyl-9-(4-biphenyl)-10-bromoanthracene
  参考文献：
  名称：

  Unsymmetrically amorphous 9,10-disubstituted anthracene derivatives for high-efficiency blue organic electroluminescence devices

  摘要：

  Two unsymmetrically amorphous 9,10-disubstituted anthracene derivatives have been synthesized and characterized. They emit the light in the blue region and possess glass transition temperature of 132.5 degrees C and 133.8 degrees C. The scanning electron microscope (SEM) was employed in studying the thin-film morphological stability of the two unsymmetrical isomers. These two compounds were fabricated into typical trilayers devices with pure blue lighting performance. In addition, a series of highly efficient and stable sky blue devices doped with a sky blue dopant BUBD-1 have been fabricated by using these two isomers as the host. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2010.10.007