[Pd(TeC6H4OEt-4)2(dppe)] | 221619-14-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: [Pd(TeC6H4OEt-4)2(dppe)]
• CAS: 221619-14-3
• 化学式: C₄₂H₄₂O₂P₂PdTe₂
• 分子量: 1002.36
• InChiKey: WPKZKYGRWONNJG-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  7.01
• 重原子数：
  49.0
• 可旋转键数：
  12.0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  18.46
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  1,2-二(二苯基膦基)乙烷二氯化钯(II) 、 [Pd(TeC6H4OEt-4)2(dppe)] 、 silver perchlorate 在 MeCN 作用下， 以 丙酮 、 乙腈 为溶剂， 以71%的产率得到[Pd2(μ-TeC6H4OEt-4)2(dppe)2](ClO4)2
  参考文献：
  名称：

  Synthesis and characterisation of mono- and binuclear palladium and platinum complexes with organochalcogenides

  摘要：

  Mononuclear palladium and platinum complexes of the type M(ER)(2)((PP)-P-boolean AND) [M = Pd or Pt; ER = SPh, SC6H4Cl-4, SC6H4Me-4, SC6F5, SePh, TeC6H4OEt-4; (PP)-P-boolean AND = dppm or dppe] have been prepared and their ability to form dinuclear metal species has been demonstrated. All complexes have been characterised by multinuclear magnetic resonance (H-1, C-13, Se-77, Pt-195) spectral data. The effects of phosphine ligands and organochalcogenides are reflected in the Se-77 and Pt-195 NMR shifts. The shielding of Pt-195 NMR chemical shifts has been interpreted in terms of their binding ability to platinum. The structures of two derivatives, namely [Pd(SC6F5)(2)(dppe)] and [Pd(SePh)(2)(dppe)], have been established by X-ray crystallography. The palladium atom in each of the monomeric structures exists in a square planar geometry. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(98)00335-1
• 作为产物：
  描述：

  1,2-二(二苯基膦基)乙烷二氯化钯(II) 、 bis-(4-ethoxy-phenyl)-ditelluride 在 NaBH₄ 作用下， 以 甲醇 、 苯 为溶剂， 以52%的产率得到[Pd(TeC6H4OEt-4)2(dppe)]
  参考文献：
  名称：

  Synthesis and characterisation of mono- and binuclear palladium and platinum complexes with organochalcogenides

  摘要：

  Mononuclear palladium and platinum complexes of the type M(ER)(2)((PP)-P-boolean AND) [M = Pd or Pt; ER = SPh, SC6H4Cl-4, SC6H4Me-4, SC6F5, SePh, TeC6H4OEt-4; (PP)-P-boolean AND = dppm or dppe] have been prepared and their ability to form dinuclear metal species has been demonstrated. All complexes have been characterised by multinuclear magnetic resonance (H-1, C-13, Se-77, Pt-195) spectral data. The effects of phosphine ligands and organochalcogenides are reflected in the Se-77 and Pt-195 NMR shifts. The shielding of Pt-195 NMR chemical shifts has been interpreted in terms of their binding ability to platinum. The structures of two derivatives, namely [Pd(SC6F5)(2)(dppe)] and [Pd(SePh)(2)(dppe)], have been established by X-ray crystallography. The palladium atom in each of the monomeric structures exists in a square planar geometry. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(98)00335-1