| 1072119-27-7

• 分子结构分类: 有机化合物
• CAS: 1072119-27-7
• 化学式: C₁₅₂H₂₅₁BN₄O₁₁Zn
• 分子量: 2386.89
• InChiKey: HYYCNOJILXDCFO-HHZIPQAQSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  、 频那醇硼烷 在 (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride 、 三乙胺 作用下， 以 1,2-二氯乙烷 为溶剂， 反应 12.0h， 以84%的产率得到
  参考文献：
  名称：

  Electron- or Hole-Transporting Nature Selected by Side-Chain-Directed π-Stacking Geometry: Liquid Crystalline Fused Metalloporphyrin Dimers

  摘要：

  Novel liquid crystalline (LC) semiconductors were prepared from the copper complex of a fused porphyrin dimer as the electroactive core by attaching to its periphery dodecyl and semifluoroalkyl side chains site-specifically (P P-hetero) and semifluoroalkyl side chains alone (P P-homo). The former and latter formed rectangular columnar and orthorhombic LC mesophases, respectively, where the stacking geometries of the pi-conjugated core are quite different from one another. Although the pi-electronic properties of the core units in P P-hetero and P P-homo in solution are substantially identical to one another, transient photocurrent profiles of their LC states under time-of-flight conditions clearly showed that P P-hetero behaves as an n-type semiconductor, whereas P P-homo, in contrast, behaves as a p-type semiconductor.

  DOI：

  10.1021/ja201272t