[Ni(2-ethoxy-6-[(2-isopropylamino-ethylimino)methyl]phenol](NCS)2 | 1206545-09-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: [Ni(2-ethoxy-6-[(2-isopropylamino-ethylimino)methyl]phenol](NCS)2
• CAS: 1206545-09-6
• 化学式: C₃₀H₄₄N₆NiO₄S₂
• 分子量: 675.539
• InChiKey: QOLROMOQHCWKOW-FQHAUYLTSA-N

反应信息

• 作为产物：
  描述：

  硫氰酸铵 、 2-ethoxy-6-[((2-isopropylamino)ethylimino)methyl]phenol 、 nickel(II) acetate tetrahydrate 以 乙醇 为溶剂， 以71.5%的产率得到[Ni(2-ethoxy-6-[(2-isopropylamino-ethylimino)methyl]phenol](NCS)2
  参考文献：
  名称：

  Syntheses and Crystal Structures of Two Copper(II) and Nickel(II) Complexes with 2-Ethoxy-6-[(2-isopropyl-aminoethylimino)methyl]phenol

  摘要：

  Two mononuclear Schiff base copper(II) and nickel(II) complexes, [CuL2]2NCS (1) and [NiL2(NCS)2] (2) (L = 2-ethoxy-6-[(2-isopropylaminoethylimino)methyl]phenol), have been obtained from the similar synthetic procedures and the Schiff base ligand, but with different metal salts. The complexes were characterized by elemental analysis, IR and single crystal X-ray diffraction. There exists crystallographic imposed center of inversion in each of the complexes. The copper(II) atom in (1) is four-coordinated in a square-planar geometry by two phenolate O and two imine N atoms from two Schiff base ligands, with the thiocyanate groups acting as counteranions. The nickel(II) aotm in (2) is six-coordinated in an octahedral geometry by two phenolate O and two imine N atoms from two Schiff base ligands, and by two N atoms from two thiocyanate ligands.

  DOI：

  10.1080/15533170802683248