| 1259289-15-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• CAS: 1259289-15-0
• 化学式: C₁₁H₁₉N₄O
• 分子量: 223.298
• InChiKey: XWEWUFLKTWGCJS-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  在 硫脲 作用下， 以 甲醇 为溶剂， 生成
  参考文献：
  名称：

  Electrochemistry of nitronyl and imino nitroxides

  摘要：

  Redox potentials of a wide group of azolyl-substituted nitronyl and imino nitroxides were determined by classic cyclic voltammetry (CV). Conclusions have been made for this group of compounds, and their peculiarities were emphasized in comparison with methyl-, phenyl-, iodo-, and cyano-substituted nitroxides.

  DOI：

  10.1134/s0036024409110284

文献信息

• Cyclic voltammetry of nitronyl- and iminonitroxyls detected by electron spin resonance
  作者：M. K. Kadirov、E. V. Tret’yakov、Yu. G. Budnikova、K. V. Kholin、M. I. Valitov、V. N. Vavilova、V. I. Ovcharenko、R. Z. Sagdeev、O. G. Sinyashin

  DOI：10.1134/s0036024409120280

  日期：2009.1

  The combined cyclic voltammetry method (cyclic voltammetry detected by electron spin resonance, CVA-DESR CVA) was applied to study the electrochemical reactions of nitronyl- and iminonitroxyls (NN and IN) and to estimate the diffusion and absorption characteristics of their products. The ESR method yielded the hyperfine structure constants, including C-13. Even if exposed to lower temperature, all the studied NN were shown to spontaneously lose oxygen and to convert gradually into the relevant IN. For each specific NN, the combined CVA-DESR CVA experiments found the reduction potential value at which it can be virtually completely converted into the relevant IN.