3,3-di(4-methoxyphenyl)-11-morpholino-13,13-dimethyl-3H,13H-indeno[2',3':3,4]naphtho[1,2-b]pyran | 761409-08-9

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 黄酮类化合物
• 英文名称: 3,3-di(4-methoxyphenyl)-11-morpholino-13,13-dimethyl-3H,13H-indeno[2',3':3,4]naphtho[1,2-b]pyran
• 英文别名: 4-[5,5-Bis(4-methoxyphenyl)-21,21-dimethyl-6-oxapentacyclo[12.7.0.02,7.08,13.015,20]henicosa-1(14),2(7),3,8,10,12,15(20),16,18-nonaen-18-yl]morpholine
• CAS: 761409-08-9
• 化学式: C₄₀H₃₇NO₄
• 分子量: 595.738
• InChiKey: JZQZZGWPJRPHCQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.9
• 重原子数：
  45
• 可旋转键数：
  5
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  40.2
• 氢给体数：
  0
• 氢受体数：
  5

文献信息

• Indeno-fused photochromic naphthopyrans, naphthols and photochromic articles
  申请人：——

  公开号：US20040185255A1

  公开（公告）日：2004-09-23

  Described are photochromic materials of indeno [2′,3′:3,4]naphtho[1,2-b]pyran structure, characterized in that they have a nitrogen or sulfur containing substituent at the 11-position ring atom, are substantially free of spiro-substituents at the 13-position and have been adapted to provide an increase in the sensitivity, visible lambda max or a combination thereof as measured in the Indenonaphthopyran Photochromic Performance Test. Optional substituents can be present at the other positions of the indeno [2′,3′:3,4]naphtho [1,2-b]pyran structure. Also described are naphthols used to produce the photochromic materials and photochromic articles that contain or that have coatings containing at least one of the novel photochromic materials or combinations thereof with other photochromic materials.

  本文描述了一种吲哚并［2′，3′：3,4］萘［1,2-b］吡喃结构的光致变色材料，其特征在于它们在11位环原子处具有含氮或硫的取代基，基本上不含有13位螺旋取代基，并且已经适应了在Indenonaphthopyran光致变色性能测试中测量的灵敏度、可见λmax或两者的增加。该吲哚并［2′，3′：3,4］萘［1,2-b］吡喃结构的其他位置可以存在可选的取代基。本文还描述了用于生产光致变色材料的萘酚以及包含至少一种新型光致变色材料或与其他光致变色材料的组合的光致变色制品或具有涂层的光致变色制品。
• CHROMENE COMPOUND
  申请人：Takahashi Toshiaki

  公开号：US20140034884A1

  公开（公告）日：2014-02-06

  A chromene compound which develops a color of a neutral tint and has little initial coloration, high double peak characteristic and high color development sensitivity, rarely experiences the reduction of color optical density though it has high fading speed, is excellent in the durability of photochromic properties and can dissolve in a monomer composition which will become a substrate for optical articles in a high concentration, and a photochromic curable composition comprising the chromene compound and polymerizable monomers. The chromene compound is represented by the following formula (1). (wherein R 3 at the 11-position is a second sulfur-containing substituent selected from the group consisting of thiol group, alkylthio group, alkoxyalkylthio group, haloalkylthio group, cycloalkylthio group, arylthio group, heteroarylthio group, sulfonyl group and sulfinyl group, R 1 and R 2 at the 6-position and the 7-position are a combination of an aryl group or a heteroaryl group and an electron donating group having a Hammett constant σ p of −0.1 or less, or R 1 and/or R 2 is a first sulfur-containing substituent selected from thiol group, alkylthio group, alkoxyalkylthio group, haloalkylthio group, cycloalkylthio group, arylthio group and heteroarylthio group.).

  一种含有色素的咔喱环化合物，具有中性色调和较小的初始着色度，高双峰特性和高颜色发展灵敏度，即使具有高褪色速度，也很少经历颜色光密度的降低，具有耐光性的优异性能，并且可以在单体组成物中高浓度溶解，用作光学制品的基板，以及包含该咔喱环化合物和可聚合单体的光致变色固化组合物。该咔喱环化合物由以下式（1）表示。（其中，在11位的R3是来自以下基团的第二个含硫取代基：硫醇基，烷基硫基，烷氧基烷基硫基，卤代烷基硫基，环烷基硫基，芳基硫基，杂环芳基硫基，磺酰基和亚磺酰基，在6位和7位的R1和R2是芳基或杂环芳基和具有Hammett常数σp小于-0.1的电子供体基团的组合，或者R1和/或R2是来自以下基团的第一个含硫取代基：硫醇基，烷基硫基，烷氧基烷基硫基，卤代烷基硫基，环烷基硫基，芳基硫基和杂环芳基硫基。）
• INDENO-FUSED PHOTOCHROMIC NAPHTHOPYRANS, NAPHTHOLS AND PHOTOCHROMIC ARTICLES
  申请人：TRANSITIONS OPTICAL, INC.

  公开号：EP1606274B1

  公开（公告）日：2018-08-08
• Photochromic articles that activate behind ultraviolet radiation blocking transparencies and methods for preparation
  申请人：——

  公开号：US20040185268A1

  公开（公告）日：2004-09-23

  Described are photochromic articles that include a substrate and at least one photochromic material adapted to change from an unactivated state to an activated state by exposure to radiation substantially in a wavelength range from 380 to 410 nanometers (nm) when measured over a wavelength range of from 380 to 700 nm. The photochromic articles demonstrate a photochromic response when activated behind an ultraviolet blocking transparency such as an automotive windshield. For example, the photochromic articles retain at least 12 percent of the activation measured as change in optical density or delta OD under outdoor simulating conditions in the Outdoor Test when tested under conditions simulating an eyeglass wearer behind an automotive windshield in the Behind the Windshield Test. Methods for producing the aforedescribed photochromic articles are also described.
• Naphthols useful for preparing indeno-fused photochromic naphthopyrans
  申请人：Walters W. Robert

  公开号：US20070155964A1

  公开（公告）日：2007-07-05

  Described are naphthols useful in the manufacture of novel indeno-fused photochromic naphthopyran materials.