1-(2,4,6-tribromo-phenylazo)-[2]naphthol | 84317-74-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 1-(2,4,6-tribromo-phenylazo)-[2]naphthol
• 英文别名: 1-(2,4,6-Tribrom-phenylazo)-[2]naphthol；(2.4.6-Tribrom-benzol)-(1 azo 1)-naphthol-(2)
• CAS: 84317-74-8
• 化学式: C₁₆H₉Br₃N₂O
• 分子量: 484.972
• InChiKey: UUNSTBBCDOTEHB-QZQOTICOSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.25
• 重原子数：
  22.0
• 可旋转键数：
  2.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  44.95
• 氢给体数：
  1.0
• 氢受体数：
  3.0

反应信息

• 作为产物：
  描述：

  2,4,6-三溴苯胺 在 氯仿 、 BF₃-N₂O₃ 作用下， 生成 1-(2,4,6-tribromo-phenylazo)-[2]naphthol
  参考文献：
  名称：

  Bachman; Hokama, Journal of the American Chemical Society, 1957, vol. 79, p. 4370,4372

  摘要：

  DOI：

文献信息

• Orton, Journal of the Chemical Society, 1903, vol. 83, p. 808
  作者：Orton

  DOI：——

  日期：——
• Microporous Polymers, Methods for the Preparation Thereof, and Uses Thereof
  申请人：Cooper Andrew

  公开号：US20100240781A1

  公开（公告）日：2010-09-23

  A method for preparing a conjugated microporous polymer comprises the coupling of an alkynyl aryl monomer having a plurality of terminal alkyne groups with an iodo- or bromo-aryl monomer having a plurality of halogen atoms in the presence of a palladium (0) catalyst. The conjugated microporous polymer comprises nodes comprising at least one aryl unit and struts comprising at least one alkyne unit and at least one aryl unit, wherein a node is bonded from its aryl unit or units to at least two struts via alkyne units. Such polymers are useful in numerous areas such as separations, controlled release, gas storage and supports for catalysts.
• US8809409B2
  申请人：——

  公开号：US8809409B2

  公开（公告）日：2014-08-19
• US9309364B2
  申请人：——

  公开号：US9309364B2

  公开（公告）日：2016-04-12
• [EN] MICROPOROUS POLYMERS, METHODS FOR THE PREPARATION THEREOF, AND USES THEREOF<br/>[FR] POLYMÈRES MICROPOREUX, LEURS PROCÉDÉS DE PRÉPARATION ET LEURS UTILISATIONS
  申请人：ULIVE ENTPR LTD

  公开号：WO2009022187A1

  公开（公告）日：2009-02-19

  A method for preparing a conjugated microporous polymer comprises the coupling of an alkynyl aryl monomer having a plurality of terminal alkyne groups with an iodo-or bromo- aryl monomer having a plurality of halogen atoms in the presence of a palladium (0) catalyst. The conjugated microporous polymer comprises nodes comprising at least one aryl unit and struts comprising at least one alkyne unit and at least one aryl unit, wherein a node is bonded from its aryl unit or units to at least two struts via alkyne units. Such polymers are useful in numerous areas such as separations, controlled release, gas storage and supports for catalysts.