(E)-9-Hydroxy-11-heptadecene | 104285-96-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: (E)-9-Hydroxy-11-heptadecene
• 英文别名: (E)-heptadec-6-en-9-ol
• CAS: 104285-96-3
• 化学式: C₁₇H₃₄O
• 分子量: 254.456
• InChiKey: CJLDXNNYPSYBSM-ACCUITESSA-N

反应信息

• 作为反应物：
  描述：

  (E)-9-Hydroxy-11-heptadecene 在 重铬酸吡啶 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 3.0h， 以93%的产率得到(E)-Heptadec-6-en-9-one
  参考文献：
  名称：

  Pyridinium Dichromate in Organic Chemistry: A New Synthesis of Enedicarbonyl Compounds

  摘要：

  乙二酮化合物（2-烯-1,4-二酮）通过以吡啶二铬酸盐在二甲基甲酰胺中氧化1-取代的3-烯醇（同烯丙醇）来制备。该反应经过3-烯基酮作为中间体进行，在某些情况下，反应时间较短时可以分离得到这些中间体。

  DOI：

  10.1055/s-1985-31419

文献信息

• PHOTO BIOCATALYTIC SYNTHESIS OF SECONDARY FATTY ALCOHOLS FROM UNSATURATED FATTY ACIDS
  申请人：Technische Universiteit Delft

  公开号：EP4028533A1

  公开（公告）日：2022-07-20
• [EN] PHOTO BIOCATALYTIC SYNTHESIS OF SECONDARY FATTY ALCOHOLS FROM UNSATURATED FATTY ACIDS<br/>[FR] SYNTHÈSE PHOTO-BIOCATALYTIQUE D'ALCOOLS GRAS SECONDAIRES À PARTIR D'ACIDES GRAS INSATURÉS
  申请人：UNIV DELFT TECH

  公开号：WO2021049932A1

  公开（公告）日：2021-03-18

  A photo enzymatic cascade reaction to transform unsaturated fatty acids into secondary fatty alcohols, and in particular into enantiomerically pure secondary fatty alcohols is disclosed. In a first hydroxyl introduction stage the unsaturated fatty acid is hydrated and/or hydroxylated with a first enzyme to provide a fatty hydroxy acid. The second stage comprises decarboxylation of the intermediate hydroxyacid by a photoactivated decarboxylase. A broad range of (poly)unsaturated fatty acids can be transformed into enantiomerically pure fatty alcohols in a simple one-pot two-step approach.