Ru2(N,N'-di(m-methoxyphenyl)formamidinato)3(N,N'-dimethyl-4-C2Si(i)Pr3-benzamidinato)(C4SiMe3)2 | 743476-71-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: Ru2(N,N'-di(m-methoxyphenyl)formamidinato)3(N,N'-dimethyl-4-C2Si(i)Pr3-benzamidinato)(C4SiMe3)2
• CAS: 743476-71-3
• 化学式: C₇₉H₉₄N₈O₆Ru₂Si₃
• 分子量: 1538.06
• InChiKey: ZPGLWTSGNARMBX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  Ru2(N,N'-di(m-methoxyphenyl)formamidinato)3(N,N'-dimethyl-4-C2Si(i)Pr3-benzamidinato)Cl 、 (4-trimethylsilyl-1,3-butadiynyl)lithium 以 四氢呋喃 为溶剂， 以43%的产率得到Ru2(N,N'-di(m-methoxyphenyl)formamidinato)3(N,N'-dimethyl-4-C2Si(i)Pr3-benzamidinato)(C4SiMe3)2
  参考文献：
  名称：

  Postmetalation Ligand Modification on the Periphery of a Diruthenium Compound:  Toward Novel Metallayne Scaffoldings

  摘要：

  A diruthenium compound bearing a peripheral iodo substituent cross-couples with acetylenes under Sonogashira conditions to yield a novel family of diruthenium compounds bearing a peripheral alkyne functionality, which can be further functionalized at the axial positions via a reaction with lithiated butadiynyl.

  DOI：

  10.1021/om049702d