1-N,1-N,1-N',1-N'-tetrakis(trimethylsilyl)-2H-azagermolo[1,5-a]pyridine-1,1-diamine | 172609-32-4

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机含氧阴离子化合物
• 英文名称: 1-N,1-N,1-N',1-N'-tetrakis(trimethylsilyl)-2H-azagermolo[1,5-a]pyridine-1,1-diamine
• CAS: 172609-32-4
• 化学式: C₁₉H₄₃GeN₃Si₄
• 分子量: 498.503
• InChiKey: PSDBKUDEXOMBOQ-UHFFFAOYSA-N

物化性质

• 沸点：
  433.1±38.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-乙烯基吡啶 、 bis[bis(trimethylsilyl)amino]germanium(II) 以 氘代苯 为溶剂， 以95%的产率得到1-N,1-N,1-N',1-N'-tetrakis(trimethylsilyl)-2H-azagermolo[1,5-a]pyridine-1,1-diamine
  参考文献：
  名称：

  Synthesis of a Novel Cyclic Germanium Enamine from Germylene and 2-Vinylpyridine and Its Stereoselective Aldol Type Reaction with Aldehydes

  摘要：

  A novel cyclic germanium(IV) enamine 3 has been prepared by the reaction of a germylene, bis[bis(trimethylsilyl)aminato]germanium (1), and 2-vinylpyridine (2). The aldol type reaction of the resulting enamine with various aldehydes 4 gave condensation products of 4,5-disubstituted 1-oxa-2-germacyclopentane derivatives 5. The reaction proceeds in a stereoselective manner to give trans products when aliphatic aldehydes were used as electrophiles. In the case of using aromatic aldehydes, cis isomers predominate. The preferential formation of a cis or traits isomer was explained by assuming an acyclic transition state for the aldol type reaction.

  DOI：

  10.1021/om00012a020