{molybdenum(III)(2-methylimidazole)3Br3} | 135289-29-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: {molybdenum(III)(2-methylimidazole)3Br3}
• CAS: 135289-29-1
• 化学式: C₁₂H₁₈Br₃MoN₆
• 分子量: 581.967
• InChiKey: FTDXYYODWHKRTH-UHFFFAOYSA-K

反应信息

• 作为产物：
  描述：

  2-甲基咪唑 、 ammonium pentabromoaquomolybdate(III) 以 盐酸 、 甲醇 、 丙酮 为溶剂， 生成 {molybdenum(III)(2-methylimidazole)3Br3}
  参考文献：
  名称：

  Molybdenum(III) complexes with some imidazoles

  摘要：

  The synthesis and characterization of complexes of stoichiometry [MoL3X3] (L = imidazole, 2-methylimidazole, benzimidazole or 2-methylbenzimidazole and X = Cl-, Br- or NCS-) are described. The effective magnetic moments (3.68-3.78 BM) are characteristic of octahedral molybdenum(III). The C = N stretching frequency of the ligands shift to higher frequency in the complexes, suggesting that tertiary nitrogen is the active site of coordination of the ligand (L). The nu(CN) and nu(CS) bands of thiocyanate complexes are diagnostic of N-bonded thiocyanate.

  DOI：

  10.1016/s0277-5387(00)80151-5