Disclosed are a Z-N catalyst for α-olefin polymerization and an application thereof, specifically, an industrial production catalyst consisting of (A) a solid catalyst component, (B) a cocatalyst organoaluminum compound and (C) an external electron donor compound and used for α-olefin polymerization or copolymerization processes. The catalyst component is prepared from a transition metal such as titanium and magnesium and a composite aromatic diacid diester/1,3-diether as an internal electron donor. One or more organoaluminum compounds or a mixture thereof serve as the cocatalyst. One or more structure control agent hydrocarbyl alkoxysilicons are compounded with one or more activity regulator organic acid esters as the external electron donor capable of automatically adjusting the polymerization rate. The Z-N catalyst is used for α-olefin polymerization/copolymerization, and can automatically adjust the polymerization rate at a higher polymerization temperature so as to maintain stable operation of a reactor.
公开了一种用于α-烯烃聚合的Z-N催化剂及其应用,具体地说,是一种工业生产催化剂,由(A)固体催化剂组分、(B)助催化剂
有机铝化合物和(C)外部电子供体化合物组成,用于α-烯烃聚合或共聚合过程。催化剂组分由过渡
金属(如
钛和
镁)和作为内部电子供体的复合芳香族二酸二酯/1,3-
二醚制备而成。一种或多种
有机铝化合物或其混合物作为助催化剂。一种或多种结构控制剂烃基烷氧基
硅酮与一种或多种活性调节剂有机酸酯复合,作为外部电子供体,能够自动调节聚合速率。Z-N 催化剂用于 α 烯烃聚合/共聚,可在较高的聚合温度下自动调节聚合速率,以保持反应器的稳定运行。