3-苯氧基苄基 (1R-顺式)-2,2-二甲基-3-(2-甲基丙-1-烯基)环丙烷羧酸酯 | 51186-88-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: 3-苯氧基苄基 (1R-顺式)-2,2-二甲基-3-(2-甲基丙-1-烯基)环丙烷羧酸酯
• 中文别名: 3-苯氧基苄基(1R-顺式)-2,2-二甲基-3-(2-甲基丙-1-烯基)环丙烷羧酸酯；(3-苯氧苯基)乙酸-2,2-二甲基-3-(2-甲基-1-丙烯基)环丙基酯速灭灵；苯醚菊酯
• 英文名称: 1R-cis-phenothrin
• 英文别名: d-cis-Phenothrin；(3-phenoxyphenyl)methyl (1R,3S)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate
• CAS: 51186-88-0；74430-92-5
• 化学式: C₂₃H₂₆O₃
• 分子量: 350.458
• InChiKey: SBNFWQZLDJGRLK-SFTDATJTSA-N

物化性质

• 溶解度：
  氯仿（微溶）、乙酸乙酯（微溶）
• 物理描述：
  PALE YELLOW-TO-YELLOW-BROWN LIQUID.
• 密度：
  Relative density (water = 1): 1.06
• 蒸汽压力：
  Vapor pressure, Pa at 20 °C:

计算性质

• 辛醇/水分配系数(LogP)：
  6.2
• 重原子数：
  26
• 可旋转键数：
  7
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.35
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  (1R,cis)-2,2-dimethyl-3-(2-oxopropyl)cyclopropane-1-carboxylic acid 、 3-苯氧基苄氯 、 potassium hydrogencarbonate 、 甲基碘化镁 、 水 、 对甲苯磺酸 生成 3-苯氧基苄基 (1R-顺式)-2,2-二甲基-3-(2-甲基丙-1-烯基)环丙烷羧酸酯
  参考文献：
  名称：

  KRASUTSKIJ, P. A.;FOKIN, A. A.;KROTOV, V. V.;BAULA, O. P.;YURCHENKO, A. G+

  摘要：

  DOI：

文献信息

• Seed treatment with combinations of pyrethrins/pyrethroids and thiamethoxam
  申请人：Monsanto Technology, LLC

  公开号：EP1844655A2

  公开（公告）日：2007-10-17

  A method of preventing damage to the seed and/or shoots and foliage of a plant by a pest includes treating the seed from which the plant grows with a composition that includes a combination of thiamethoxam and at least one pyrethrin or synthetic pyrethroid which is selected from the group consisting of taufluvalinate, flumethrin, trans-cyfluthrin, kadethrin, bioresmethrin, tetramethrin, phenothrin, empenthrin, cyphenotrin, prallethrin, imiprothrin, allethrin and bioallethrin. The treatment is applied to the unsown seed. In another embodiment, the seed is a transgenic seed having at least one heterologous gene encoding for the expression of a protein having pesticidal activity against a first pest and the composition has activity against at least one second pest. Treated seeds are also provided.

  一种防止害虫对植物种子和/或嫩枝和叶片造成损害的方法，包括用一种组合物处理生长植物的种子，该组合物包括噻虫嗪和至少一种拟除虫菊酯或合成拟除虫菊酯的组合物，该拟除虫菊酯或合成拟除虫菊酯选自由氟虫腈组成的组、氟氯氰菊酯、反式氟氯氰菊酯、氯氰菊酯、生物除害菊酯、四氯氰菊酯、苯醚菊酯、氰戊菊酯、氯氰菊酯、炔丙菊酯、烯丙菊酯和生物烯丙菊酯。处理方法适用于未播种的种子。在另一个实施方案中，种子是转基因种子，具有至少一种异源基因，编码表达对第一种害虫具有杀虫活性的蛋白质，组合物对至少一种第二种害虫具有杀虫活性。还提供了经过处理的种子。
• Compositions and methods for deploying a transgenic refuge as a seed blend
  申请人：Head Graham

  公开号：US10036036B1

  公开（公告）日：2018-07-31

  Methods and compositions for deploying refuge seeds together with transgenic crop seeds are provided. The refuge seeds can be non-transgenic seeds of a similar variety to that of the transgenic crop seeds, or the refuge seeds can be a transgenic variety, but in either case lacking a transgenic trait conferring pest protection found in the transgenic crop seeds.

  本文提供了将避难种子与转基因作物种子一起播种的方法和组合物。保护种子可以是与转基因作物种子品种相似的非转基因种子，或者保护种子可以是转基因品种，但无论哪种情况，都缺乏转基因作物种子中具有害虫保护功能的转基因性状。
• Proteins toxic to Hemipteran insect species
  申请人：Monsanto Technology LLC

  公开号：US10188115B2

  公开（公告）日：2019-01-29

  The present invention discloses Hemipteran insect inhibitory proteins, methods of using such proteins, nucleotide sequences encoding such proteins, methods of detecting and isolating such proteins, and their use in agricultural systems.

  本发明公开了半翅目昆虫抑制蛋白、使用这种蛋白的方法、编码这种蛋白的核苷酸序列、检测和分离这种蛋白的方法以及它们在农业系统中的用途。
• Proteins toxic to hemipteran insect species
  申请人：Monsanto Technology LLC

  公开号：US10897910B2

  公开（公告）日：2021-01-26

  The present invention discloses Hemipteran insect inhibitory proteins, methods of using such proteins, nucleotide sequences encoding such proteins, methods of detecting and isolating such proteins, and their use in agricultural systems.

  本发明公开了半翅目昆虫抑制蛋白、使用这种蛋白的方法、编码这种蛋白的核苷酸序列、检测和分离这种蛋白的方法以及它们在农业系统中的用途。
• Method of controlling the release of agricultural active ingredients from treated plant seeds
  申请人：Monsanto Technology, L.L.C.

  公开号：US20020134012A1

  公开（公告）日：2002-09-26

  A method of controlling the release rate of an agricultural active ingredient from a seed that has been treated with that active includes providing a seed that has been treated with the active ingredient, applying to the treated seed a film that includes an emulsion of a polymer in a liquid in which both the agricultural active ingredient and the polymer have low levels of solubility, and then curing the film to form a water insoluble polymer coating on the surface of the treated seed. Seeds that have been treated by this method are also provided.

  一种控制农用活性成分从用该活性成分处理过的种子中释放速率的方法包括：提供一粒用该活性成分处理过的种子，在该处理过的种子上涂抹一层薄膜，该薄膜包括聚合物在液体中的乳液，在该液体中农用活性成分和聚合物的溶解度都很低，然后固化该薄膜，在该处理过的种子表面形成一层不溶于水的聚合物包衣。还提供了用这种方法处理过的种子。