S-benzyl-N-glycyl-DL-penicillamine | 100876-47-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: S-benzyl-N-glycyl-DL-penicillamine
• 英文别名: S-benzyl-N-glycyl-DL-penicillamine；S-benzyl-N-glycyl-penicillamine；S-Benzyl-N-glycyl-DL-penicillamin；(+/-)-α-Aminoacetamino-β-benzylmercapto-isovaleriansaeure；S-Benzyl-N-glycyl-penicillamin
• CAS: 100876-47-9
• 化学式: C₁₄H₂₀N₂O₃S
• 分子量: 296.39
• InChiKey: REQWNMQRUCTPKP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.23
• 重原子数：
  20.0
• 可旋转键数：
  7.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  92.42
• 氢给体数：
  3.0
• 氢受体数：
  4.0

反应信息

• 作为产物：
  描述：

  S-benzyl-D,L-penicillamine 在 sodium hydroxide 、 一水合肼 、 溶剂黄146 作用下， 反应 2.0h， 生成 S-benzyl-N-glycyl-DL-penicillamine
  参考文献：
  名称：

  King et al., Journal of the Chemical Society, 1959, p. 2259,2262

  摘要：

  DOI：

文献信息

• Coesite inclusions in zircon from gneisses identified by laser Raman microspectrometer in ultrahigh pressure zone of Dabie Mountains, China
  作者：Jingbo Liu、Kai Ye、Bolin Cong、Maruyama Shegnori、Hongrui Fan

  DOI：10.1007/bf02901171

  日期：2001.11

  The mineral inclusions in zircon from gneisses in ultra-high pressure (UHP) zone of the Dable Mountains were identified by using a laser Raman microspectrometer. Coesite occurs as inclusions in zircons from all types of gneiss. Other important minerals, such as jadeite, omphacite, aragonite, barite, and anhydrite were also found as inclusion minerals. These discoveries indicate that (i) gneissic country rocks had metamorphosed at the same time as the enclosed eclogites; and (ii) SO4-2-bearing fluids were present in the UHP metamorphic process, which is manifested by occurrence of barite and anhydrite coexisting with coesite.