3,9-Dichloro-chrysene | 36288-16-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 3,9-Dichloro-chrysene
• 英文别名: 3,9-Dichlorochrysene
• CAS: 36288-16-1
• 化学式: C₁₈H₁₀Cl₂
• 分子量: 297.183
• InChiKey: ZRNJCWGDFQRPAN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.9
• 重原子数：
  20
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  (E,E,E)-1,6-di(4-chlorophenyl)hexa-1,3,5-triene 在 碘 作用下， 以 苯 为溶剂， 生成 3,9-Dichloro-chrysene
  参考文献：
  名称：

  Photocyclization Reactions of Aryl Polyenes. V. Photochemical Synthesis of Substituted Chrysenes

  摘要：

  1,6-二对位取代苯基-1,3,5-己三烯的光环化-氧化反应产生了3,9-二取代蒽。类似地，对1-对位取代苯基-6-苯基-1,3,5-己三烯的辐射处理产生了3-取代蒽。通过1-α-萘基-2-对位取代苯乙烯的光环化-氧化，高产率地独立制备了3-取代蒽。

  DOI：

  10.1139/v72-081

文献信息

• COMPOUND FOR ORGANIC THIN FILM TRANSISTOR AND ORGANIC THIN FILM TRANSISTOR USING THE SAME
  申请人：Nakano Yuki

  公开号：US20110210319A1

  公开（公告）日：2011-09-01

  A compound for an organic thin film transistor represented by the following formula ( 1 ): wherein at least one pair of adjacent two groups of R 1 , R 3 , R 5 and R 7 is bonded to each other to form a substituted or unsubstituted aromatic hydrocarbon ring having 6 to 60 carbon atoms or a substituted or unsubstituted aromatic heterocyclic ring having 3 to 60 carbon atoms, the ring being fused to the ring to which the groups are bonded; and at least one pair of adjacent two groups of R 2 , R 4 , R 6 and R 8 is bonded to each other to form a substituted or unsubstituted aromatic hydrocarbon ring having 6 to 60 carbon atoms or a substituted or unsubstituted aromatic heterocyclic ring having 3 to 60 carbon atoms, the ring being fused to the ring to which the groups are bonded.
• US8785915B2
  申请人：——

  公开号：US8785915B2

  公开（公告）日：2014-07-22
• Photocyclization Reactions of Aryl Polyenes. V. Photochemical Synthesis of Substituted Chrysenes
  作者：Clifford C. Leznoff、Roger J. Hayward

  DOI：10.1139/v72-081

  日期：1972.2.15

  The photocyclization-oxidation reaction of 1,6-di-p-substituted-phenyl-1,3,5-hexatrienes gave 3,9-disubstituted-chrysenes. Similarly, irradiation of 1-p-substituted-phenyl-6-phenyl-1,3,5-hexatrienes yielded 3-substituted-chrysenes. The 3-substituted-chrysenes were independently prepared in a high yield by the photocyclization-oxidation of 1-α-naphthyl-2-p-substituted-phenylethylenes.

  1,6-二对位取代苯基-1,3,5-己三烯的光环化-氧化反应产生了3,9-二取代蒽。类似地，对1-对位取代苯基-6-苯基-1,3,5-己三烯的辐射处理产生了3-取代蒽。通过1-α-萘基-2-对位取代苯乙烯的光环化-氧化，高产率地独立制备了3-取代蒽。