(1R)-1-{(1R,2S)-2-acetyl-2-hydroxy-1-methyl-5-oxocyclopentyl}-2-[(6S,8aR)-6-{[2,6-dideoxy-3-O-methyl-α-L-ribo-hexopyranosyl-(1->4)-2,6-dideoxy-3-O-methyl-β-D-ribo-hexopyranosyl-(1->4)-2,6-dideoxy-3-O-methyl-α-L-lyxo-hexopyranosyl-(1->4)-2,6-dideoxy-β-D-ribo-hexopyranosyl]oxy}-8a-methyl-2-oxo-1,2,3,5,6,7,8,8a-octahydronaphthalen-1-yl]ethyl (2E)-3-phenylprop-2-enoate | 1206191-06-1

• 分子结构分类: 有机化合物 - 脂质和类脂质分子
• 英文名称: (1R)-1-{(1R,2S)-2-acetyl-2-hydroxy-1-methyl-5-oxocyclopentyl}-2-[(6S,8aR)-6-{[2,6-dideoxy-3-O-methyl-α-L-ribo-hexopyranosyl-(1->4)-2,6-dideoxy-3-O-methyl-β-D-ribo-hexopyranosyl-(1->4)-2,6-dideoxy-3-O-methyl-α-L-lyxo-hexopyranosyl-(1->4)-2,6-dideoxy-β-D-ribo-hexopyranosyl]oxy}-8a-methyl-2-oxo-1,2,3,5,6,7,8,8a-octahydronaphthalen-1-yl]ethyl (2E)-3-phenylprop-2-enoate
• 英文别名: 3-O-α-L-cymaropyranosyl-(1->4)-β-D-cymaropyranosyl-(1->4)-α-L-diginopyranosyl-(1->4)-β-D-cymaropyranosyl kidjoranin-8,14-dione
• CAS: 1206191-06-1
• 化学式: C₅₈H₈₄O₁₉
• 分子量: 1085.29
• InChiKey: ATLRBRNQSKLGHZ-OPJBKVMLSA-N

反应信息

• 作为产物：
  描述：

  wilfoside K1N 在 lead(IV) tetraacetate 作用下， 以 苯 为溶剂， 反应 0.5h， 以24.5 mg的产率得到(1R)-1-{(1R,2S)-2-acetyl-2-hydroxy-1-methyl-5-oxocyclopentyl}-2-[(6S,8aR)-6-{[2,6-dideoxy-3-O-methyl-α-L-ribo-hexopyranosyl-(1->4)-2,6-dideoxy-3-O-methyl-β-D-ribo-hexopyranosyl-(1->4)-2,6-dideoxy-3-O-methyl-α-L-lyxo-hexopyranosyl-(1->4)-2,6-dideoxy-β-D-ribo-hexopyranosyl]oxy}-8a-methyl-2-oxo-1,2,3,5,6,7,8,8a-octahydronaphthalen-1-yl]ethyl (2E)-3-phenylprop-2-enoate
  参考文献：
  名称：

  西洋梨的C21甾族糖苷

  摘要：

  八新的C 21甾体糖苷，命名wilfosides A-H（1 - 8，RESP），与一种已知化合物wilfoside KIN（沿9），从根分离牛心甙。在光谱分析的基础上确定了新糖苷的结构，包括1D和2D-NMR，ESI-MS技术以及将光谱数据与相关化合物的光谱数据进行了比较。

  DOI：

  10.1002/hlca.200900057