硅烷,(甲氧基苯氧基甲基)三甲基- | 17155-05-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 中文名称: 硅烷,(甲氧基苯氧基甲基)三甲基-
• 英文名称: methoxy phenoxy methyl trimethylsilane
• 英文别名: [Methoxy(phenoxy)methyl]-trimethylsilane
• CAS: 17155-05-4
• 化学式: C₁₁H₁₈O₂Si
• 分子量: 210.348
• InChiKey: YMBROPMGTUGYOL-UHFFFAOYSA-N

物化性质

• 沸点：
  254.8±30.0 °C(Predicted)
• 密度：
  0.947±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.92
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  硅烷,(甲氧基苯氧基甲基)三甲基- 、 1,2-乙二硫醇 在 三氟化硼乙醚 作用下， 以88%的产率得到2-trimethylsilyl-1,3-dithiolane
  参考文献：
  名称：

  2-Trimethylsilyl-1,3-dithiolane as a masked dithiolane anion

  摘要：

  2-Trimethylsilyl-1,3 -dithiolane, easily obtainable through transthioacetalization of corresponding silylated acetals, can be efficiently reacted, under fluoride-ion catalysis, with different organic electrophiles, leading to a general and mild functionalization protocol. This reactivity discloses the ability of compound 3 to act as a masked dithiolane anion. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(01)00771-7
• 作为产物：
  描述：

  (甲氧基甲基)三甲基硅烷 在 溴 、 N,N-二异丙基乙胺 作用下， 生成 硅烷,(甲氧基苯氧基甲基)三甲基-
  参考文献：
  名称：

  2-Trimethylsilyl-1,3-dithiolane as a masked dithiolane anion

  摘要：

  2-Trimethylsilyl-1,3 -dithiolane, easily obtainable through transthioacetalization of corresponding silylated acetals, can be efficiently reacted, under fluoride-ion catalysis, with different organic electrophiles, leading to a general and mild functionalization protocol. This reactivity discloses the ability of compound 3 to act as a masked dithiolane anion. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(01)00771-7

文献信息

• Stereoselective Functionalization of Dithiolanes and Dithianes: The First Example of an Axial Trapping
  作者：Alessandro Degl’Innocenti、Salvatore Pollicino、Antonella Capperucci、Vanda Cerè、Tiziano Nocentini

  DOI：10.1055/s-2002-33521

  日期：——

  and dithianes can be easily functionalized under fluoride ion conditions. The functionalization occurs stereoselectively, the products bearing the incoming groups in the position formerly occupied by the silyl moiety. These results lead to the first example of dithiolane and dithiane axial trapping.

  2-Silyl-1,3-dithiolanes 和 dithianes 在氟离子条件下很容易被官能化。官能化立体选择性地发生，产物在先前由甲硅烷基部分占据的位置上带有传入基团。这些结果导致了二硫戊环和二噻烷轴向捕获的第一个例子。
• Synthesis of A New Class of Sulfurated and Selenated Silyl Heterocycles
  作者：Antonella Capperucci、Damiano Tanini、Alessandro Degl’Innocenti

  DOI：10.1080/10426507.2012.727518

  日期：2013.4.1

  Abstract 2-Trimethylsilyl-1,3-thiaselenolanes and 2-trimethylsilyl-1,3-oxaselenolanes can be accessed through the reaction of a silyl acetal with β-mercapto- and β-hydroxyselenols under Lewis acid conditions. GRAPHICAL ABSTRACT

  摘要 2-Trimethylsilyl-1,3-thiaselenolanes 和2-trimethylsilyl-1,3-oxaselenolanes 可以通过甲硅烷基缩醛与β-巯基-和β-羟基硒醇在路易斯酸条件下反应获得。图形概要
• α,β-Unsaturated thioacylsilanes as efficient dienes in hetero Diels–Alder reactions
  作者：Antonella Capperucci、Alessandro Degl'Innocenti、Tiziano Nocentini、Simona Biondi、Francesca Dini

  DOI：10.1016/s0022-328x(03)00615-6

  日期：2003.11

  Reaction of several α,β-unsaturated thioacylsilanes with in situ generated thioaldehydes and thioacylsilanes affords under mild conditions a clean and regioselective access to 2-substituted 4-silyl-1,3-dithiacyclohex-4-ene derivatives, arising from an hetero-Diels–Alder reaction between two different thiocarbonyl compounds.

  几种α，β-不饱和硫代酰基硅烷与原位生成的硫代醛和硫代酰基硅烷的反应在温和条件下提供了干净和区域选择性的途径，可得自杂Diels生成的2-取代的4-甲硅烷基-1,3-二硫代环己基-4-烯衍生物–两种不同的硫代羰基化合物之间的Al光反应。