| 1202742-52-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• CAS: 1202742-52-6
• 化学式: C₃₀H₁₆
• 分子量: 376.457
• InChiKey: SEXILKYOZNBPMB-LWKGNBDESA-N

反应信息

• 作为产物：
  描述：

  在 lithium aluminium tetrahydride 、 四氯化钛 、 三乙胺 作用下， 以 四氢呋喃 为溶剂， 以48%的产率得到
  参考文献：
  名称：

  Molecular clips and tweezers with corannulene pincers

  摘要：

  Application of the synthetic methodology developed in our laboratory yields molecular clips and tweezers with corannulene pincers and cyclooctadiene or cyclooctatetraene tethers. These highly nonplanar systems possess a potential for binding guest molecules of various sizes. One of the clips, bis(benzocorannulene)[a,e]cyclooctadiene, exists in a 'open' chair conformation encapsulating solvating nitrobenzene in the solid state, while it is expected to prefer an internally pi-pi stacked twist-boat conformation in the gas phase. (c) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2009.09.177