9-[3-[6-(3-Carbazol-9-ylphenyl)-4-phenanthren-9-ylpyridin-2-yl]phenyl]carbazole | 890148-69-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 9-[3-[6-(3-Carbazol-9-ylphenyl)-4-phenanthren-9-ylpyridin-2-yl]phenyl]carbazole
• CAS: 890148-69-3
• 化学式: C₅₅H₃₅N₃
• 分子量: 737.903
• InChiKey: KBSAKXACGOTIDB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  14.5
• 重原子数：
  58
• 可旋转键数：
  5
• 环数：
  12.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  22.8
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  2,6-Bis(3-bromophenyl)-4-phenanthren-9-ylpyridine 、 咔唑 在 tris(dibenzylideneacetone)dipalladium(0) chloroform complex 三叔丁基膦 、 sodium t-butanolate 作用下， 以 氯仿 、 甲苯 为溶剂， 反应 1.5h， 生成 9-[3-[6-(3-Carbazol-9-ylphenyl)-4-phenanthren-9-ylpyridin-2-yl]phenyl]carbazole
  参考文献：
  名称：

  EP1820801

  摘要：

  公开号：

文献信息

• ORGANIC COMPOUND, CHARGE-TRANSPORTING MATERIAL, AND ORGANIC ELECTROLUMINESCENT ELEMENT
  申请人：Pioneer Corporation

  公开号：EP1820801A1

  公开（公告）日：2007-08-22

  An organic compound and a charge-transporting material which are excellent in both a hole-transporting property and an electron-transporting property and have excellent electrical oxidation/reduction durability and a high triplet excitation level are provided, and an organic electroluminescent device which uses this organic compound and has high luminous efficiency and high driving stability and long lifetime is provided. One molecule of the organic compound has two or more partial structures represented by the following Formula (I): wherein Cz denotes a carbazolyl group; Z denotes a direct link or an optional linking group; N atoms present in one molecule do not conjugate with each other excepting between N atoms in the same B1 rings; one molecule contains only one pyridine ring; one molecule contains a plurality of Q's; and Q denotes a direct link connected to G present in a moiety represented by the following Formula (II): wherein B1 ring is a six-membered aromatic heterocycle containing n N atoms as a hetero atom; n is an integer of 1 to 3; when G is linked to Q, the G denotes a direct link or an optional linking group which links to Q; when G is not linked to Q, the G denotes an aromatic hydrocarbon group; G's are bound to C atoms in ortho-position and para-position with respect to the N atom in B1 ring; and m is an integer of 3 to 5.

  本发明提供了一种在空穴传输特性和电子传输特性方面都非常出色、具有出色的电氧化/还原耐久性和高三重激发水平的有机化合物和电荷传输材料，并提供了一种使用该有机化合物的有机电致发光器件，该器件具有高发光效率、高驱动稳定性和长寿命。该有机化合物的一个分子具有下式（I）所代表的两个或多个部分结构： 其中 Cz 表示咔唑基；Z 表示直接连接或任选连接基团；存在于一个分子中的 N 原子彼此不共轭，但存在于相同 B1 环中的 N 原子间除外；一个分子只包含一个吡啶环；一个分子包含多个 Q；Q 表示与存在于下式（II）所代表的分子中的 G 相连的直接连接： 其中 B1 环为六元芳香杂环，含有 n 个 N 原子作为杂原子；n 为 1 至 3 的整数；当 G 与 Q 连接时，G 表示直接连接或与 Q 连接的任选连接基团；当 G 未与 Q 连接时，G 表示芳香烃基团；G 与 B1 环中相对于 N 原子处于正位和对位的 C 原子结合；m 为 3 至 5 的整数。
• ORGANIC ELECTROLUMINESCENT ELEMENT
  申请人：FUJIFILM Corporation

  公开号：EP2461390A1

  公开（公告）日：2012-06-06

  Provided is an organic electroluminescence device that can be driven at a low voltage, and has a high efficiency, excellent durability and a small change in chromaticity when driving at a high temperature. The organic electroluminescence device has a pair of electrodes disposed on a substrate and at least one organic layer including a light emitting layer disposed between the electrodes. The organic electroluminescence device contains a compound represented by the following Formula (1) in any one layer of the organic layers and a phosphorescence emitting material represented by the following Formula (C-1) in the light emitting layer.         (Cz)p-L-(A)q     (1) In Formula (1), Cz is a substituted or unsubstituted arylcarbazolyl group or a carbazolylaryl group, L is a single bond or a substituted or unsubstituted arylene group, a substituted or unsubstituted cycloalkylene group, or a substituted or unsubstituted aromatic heterocyclic ring, A is a substituted or unsubstituted nitrogen-containing six-membered aromatic heterocyclic ring, and each of p and q is independently an integer of 1 to 6. In Formula (C-1), each of Q1, Q2, Q3 and Q4 independently represents a ligand which is coordinated to Pt. Each of L1, L2 and L3 independently represents a single bond or a divalent linking group.

  本发明提供了一种有机电致发光器件，它可以在低电压下驱动，并且效率高、耐用性好，在高温下驱动时色度变化小。该有机电致发光器件具有一对设置在基板上的电极和至少一个设置在电极之间的包括发光层在内的有机层。有机电致发光器件在有机层的任意一层中含有下式（1）代表的化合物，在发光层中含有下式（C-1）代表的磷光发光材料。 (Cz)p-L-(A)q (1) 在式 (1) 中，Cz 是取代或未取代的芳基咔唑基团或咔唑芳基，L 是单键或取代或未取代的芳烯基团、取代或未取代的环亚烷基或取代或未取代的芳香杂环，A 是取代或未取代的含氮六元芳香杂环，p 和 q 中的每一个独立地为 1 至 6 的整数。 在式（C-1）中，Q1、Q2、Q3 和 Q4 各自独立地代表与铂配位的配体，L1、L2 和 L3 各自独立地代表单键或二价连接基团。
• Organic electroluminescent element
  申请人：Kaminaga Kuniyuki

  公开号：US10431749B2

  公开（公告）日：2019-10-01

  Disclosed is an organic electroluminescent element which is excellent with respect to luminous efficiency and driving voltage and rarely undergoes initial luminance drop. Specifically disclosed is an organic electroluminescent element which comprises, on a substrate, a pair of electrodes composed of an anode and a cathode and a light-emitting layer arranged between the electrodes, and additionally comprises at least one organic layer arranged between the light-emitting layer and the cathode, where in the light-emitting layer contains, for example, a compound (A-1), and the at least one layer arranged between the light-emitting layer and the cathode contains, for example, a compound (e-4).

  本发明公开了一种有机电致发光元件，它在发光效率和驱动电压方面都非常出色，而且很少出现初始亮度下降的情况。具体地说，本发明公开了一种有机电致发光元件，它包括位于基板上的一对由阳极和阴极组成的电极以及位于电极之间的发光层，此外还包括位于发光层和阴极之间的至少一层有机层，其中发光层含有例如化合物（A-1），而位于发光层和阴极之间的至少一层含有例如化合物（e-4）。
• EP1820801B1
  申请人：——

  公开号：EP1820801B1

  公开（公告）日：2015-04-01
• ORGANIC ELECTROLUMINESCENCE DEVICE
  申请人：Ise Toshihiro

  公开号：US20120126690A1

  公开（公告）日：2012-05-24

  As an organic electroluminescence device that has an excellent emission characteristic, suppresses a change in chromaticity when driving at a high temperature and has excellent durability, the organic electroluminescence device includes on a substrate a pair of electrodes and a light emitting layer disposed between the electrodes, in which the light emitting layer contains a compound represented by the following Formula (1) and a specific metal complex is provided. (Cz) p -L-(A) q (1) (In Formula (1), Cz represents a substituted or unsubstituted arylcarbazolyl group or a substituted or unsubstituted carbazolylaryl group. L represents a single bond, a substituted or unsubstituted arylene group, a substituted or unsubstituted cycloalkylene group or a substituted or unsubstituted aromatic heterocyclic ring. A is a substituted or unsubstituted nitrogen-containing aromatic heterocyclic six-membered ring, and each of p and q independently represent an integer of 1 to 6.)