[Hg2(bis[4-(2-pyridylmethyleneamino)phenyl]methane)2(H2O)](NO3)4 | 1253390-16-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: [Hg2(bis[4-(2-pyridylmethyleneamino)phenyl]methane)2(H2O)](NO3)4
• CAS: 1253390-16-7
• 化学式: C₅₀H₄₂Hg₂N₁₁O₁₀*NO₃
• 分子量: 1420.14
• InChiKey: BWPVIPNLESHUET-KFDZQMBJSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Hg2(bis[4-(2-pyridylmethyleneamino)phenyl]methane)2(H2O)](NO3)4 以 neat (no solvent) 为溶剂， 生成 mercury(II) oxide
  参考文献：
  名称：

  Synthesis, spectral characterization and structure of dinuclear double-helical mercury complex containing bis[4-(2-pyridylmethyleneamino)phenyl]methane ligand

  摘要：

  The bis[4-(2-pyridylmethyleneamino)phenyl]methane ligand L and it's dinuclear double-helical mercury complex, 1 have been synthesized and characterized by CHN analysis, IR and UV-Vis spectroscopy. The crystal structures of L and 1 were determined from single crystal X-ray diffraction. The molecule of ligand L is generated by a crystallographic two-fold axis and adopts an E configuration with respect to the C=N bond. The dihedral angles between the planes of the pyridine ring, chelate ring, and the benzene ring in L show coplanarity of these planes, leading to a considerable planarity of these moieties. The two phenyl rings of the diarylmethane spacer of L are inclined at an angle of 8.75 degrees to one another, so that L forms an appreciable V shape. The asymmetric unit of 1 contains two independent Hg atoms, two ligands and four nitrate anions. The ligands wrap around the two mercury canters forming a double-helical structure. Three nitrate anions act as a bidentate ligand and the other nitrate anion is uncoordinated. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.06.032
• 作为产物：
  描述：

  水 、 mercury(II) nitrate 、 (1E)-pyridin-2-yl-N-(4-(4-(((E)-pyridin-2-ylmethylidene)amino)benzyl)phenyl)methanimine 以 水 、 乙腈 为溶剂， 以75%的产率得到[Hg2(bis[4-(2-pyridylmethyleneamino)phenyl]methane)2(H2O)](NO3)4
  参考文献：
  名称：

  Synthesis, spectral characterization and structure of dinuclear double-helical mercury complex containing bis[4-(2-pyridylmethyleneamino)phenyl]methane ligand

  摘要：

  The bis[4-(2-pyridylmethyleneamino)phenyl]methane ligand L and it's dinuclear double-helical mercury complex, 1 have been synthesized and characterized by CHN analysis, IR and UV-Vis spectroscopy. The crystal structures of L and 1 were determined from single crystal X-ray diffraction. The molecule of ligand L is generated by a crystallographic two-fold axis and adopts an E configuration with respect to the C=N bond. The dihedral angles between the planes of the pyridine ring, chelate ring, and the benzene ring in L show coplanarity of these planes, leading to a considerable planarity of these moieties. The two phenyl rings of the diarylmethane spacer of L are inclined at an angle of 8.75 degrees to one another, so that L forms an appreciable V shape. The asymmetric unit of 1 contains two independent Hg atoms, two ligands and four nitrate anions. The ligands wrap around the two mercury canters forming a double-helical structure. Three nitrate anions act as a bidentate ligand and the other nitrate anion is uncoordinated. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.06.032