1-(n-butyl)-3-(2-oxopropyl)imidazolium chloride | 949925-24-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 1-(n-butyl)-3-(2-oxopropyl)imidazolium chloride
• CAS: 949925-24-0
• 化学式: C₁₀H₁₇N₂O*Cl
• 分子量: 216.711
• InChiKey: FHCRXPDCFHHHSF-UHFFFAOYSA-M

反应信息

• 作为反应物：
  描述：

  bis[dichloro(pentamethylcyclopentadienyl)iridium(III)] 、 1-(n-butyl)-3-(2-oxopropyl)imidazolium chloride 在 silver(l) oxide 作用下， 以 二氯甲烷 为溶剂， 以89%的产率得到
  参考文献：
  名称：

  Ir(III)-Induced C-Bound to N-Bound Tautomerization of a N-Heterocyclic Carbene

  摘要：

  An iridium N-heterocyclic carbene (NHC) complex with a rare hydrogen wing tip was obtained via C-N bond cleavage. The C-bound to N-bound tautomerization of this carbene cannot be achieved in this neutral 18-electron Ir(III) complex. Chloride abstraction in MeCN afforded an NHC-acetimidamide complex, where the N-bound to C-bound tautomerization of this carbene was observed in CDCl3 at 110 degrees C. Crystal structures of iridium complexes with these rare ligands were reported.

  DOI：

  10.1021/om700498w