ZINC;quinoline-2-carboxylate | 61818-65-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: ZINC;quinoline-2-carboxylate
• CAS: 61818-65-3
• 化学式: C₂₀H₁₂N₂O₄Zn
• 分子量: 409.716
• InChiKey: WNZNEKPFXJXMSK-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  1.19
• 重原子数：
  27
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  106
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  喹哪啶酸 、 zinc(II) acetate dihydrate 以 乙醇 、 水 为溶剂， 生成 ZINC;quinoline-2-carboxylate
  参考文献：
  名称：

  Synthesis and OLED Properties of Zinc Complexes Based on Quinaldic Acid

  摘要：

  Metal-chelate materials based on polycyclic aromatic ligands are attractive for tuning emission colors of organic light-emitting diodes (OLED). In this work, quinaldic acid (QA) and 8-hydroxyquinoline (HQ) were employed as organic ligands and the corresponding zinc complexes (Zn(HQA), Zn(QA), Zn(HQ)) were synthesized. The structures of Zn(HQA), Zn(QA), and Zn(HQ) were determined by H-1-NMR, C-13-NMR, FT-IR, UV-Vis and XPS. Zinc complexes showed thermal stability up to 350 degrees C under nitrogen flow by TGA. The photoluminescence (PL) was measured from DMSO solution. The Zn(HQA) emitted a yellow light around 550 nm, while Zn(HQ) emitted a green light around 500 nm. Electroluminescence (EL) device having the structure of ITO/NPB/Zn(HQA)/Liq/Al was fabricated. The device emitted a yellow light around 550 nm. The maximum luminance of 190 cd/m(2) and current of 50mA/cm(2) were observed at 15 V in the Zn(HQA)-containing device.

  DOI：

  10.1080/15421406.2014.935971

文献信息

• Metal-containing monomer dissolved mixture, metal-containing resin and antifouling paint composition
  申请人：MITSUBISHI RAYON CO., LTD.

  公开号：EP1167398A2

  公开（公告）日：2002-01-02

  A metal-containing monomer dissolved mixture comprising a reaction product of an inorganic metal compound with a carboxyl group-containing radical polymerizable monomer, an organic solvent including at least an alcohol-based solvent, and water, wherein the water content is from 0.01 to 30% by weight; a metal-containing resin obtained by copolymerizing the metal-containing monomer (A) in this dissolved mixture with the other radical-polymerizable unsaturated monomer (B); an antifouling paint composition obtained by using this metal-containing resin; and an antifouling paint composition comprising a divalent metal-containing resin (C), a compound (D) of R1-SH (wherein, R1 represents an organic group having 1 to 30 carbon atoms.), and copper oxide (E), are disclosed.

  一种含金属单体的溶解混合物，包括无机金属化合物与含羧基可自由基聚合单体的反应产物、有机溶剂（至少包括醇基溶剂）和水，其中水含量为 0.本发明公开了一种无机金属化合物与含羧基的可自由基聚合单体和水的混合物，其中水含量为 0.01 至 30% (重量)；一种含金属树脂，通过将该溶解混合物中的含金属单体 (A) 与另一种可自由基聚合的不饱和单体 (B) 共聚而获得；一种防污漆组合物，通过使用该含金属树脂而获得；以及一种防污漆组合物，包括二价含金属树脂 (C)、R1-SH 的化合物 (D) (其中，R1 代表具有 1 至 30 个碳原子的有机基团。) 和氧化铜 (E)。
• Antifouling paint composition
  申请人：MITSUBISHI RAYON CO., LTD.

  公开号：EP1707602A2

  公开（公告）日：2006-10-04

  An antifouling paint composition comprising, as a vehicle, a copolymer from a monomer mixture comprising of (a1) a metal-containing polymerizable monomer having two unsaturated groups and (b) a polymerizable monomer represented by the following formula (II): wherein R3 represents a hydrogen atom or a methyl group; R4 represents an alkyl group having 1 to 10 carbon atoms, a cycloalkyl group or a phenyl group; and R5 represents an alkyl having 1 to 10 carbon atoms, a cycloalkyl group or a phenyl group.

  一种防污漆组合物，其载体是由以下单体混合物组成的共聚物：(a1) 具有两个不饱和基团的含金属可聚合单体；(b) 下式(II)代表的可聚合单体： 其中 R3 代表氢原子或甲基；R4 代表具有 1 至 10 个碳原子的烷基、环烷基或苯基；R5 代表具有 1 至 10 个碳原子的烷基、环烷基或苯基。
• METHOD FOR PRODUCING RESIN DISPERSION FOR ANTIFOULING COATING
  申请人：Mitsubishi Rayon Co., Ltd.

  公开号：EP2520620A1

  公开（公告）日：2012-11-07

  It is an object of the present invention to provide an antifouling coating resin dispersion which has excellent storage stability and water resistance in sea water, can exhibit an antifouling effect over a long period of time, and has self-polishing properties with excellent adhesiveness. A method for producing the antifouling coating resin dispersion according to the present invention includes the steps of: producing a polymer (A) containing a divalent metal; and dispersing the polymer (A) in a dispersion medium containing water or a mixture of water and an organic solvent. The polymer (A) containing a divalent metal is obtained by subjecting 1 to 40% by mass of a divalent-metal-containing ethylenically unsaturated monomer (a1), 0 to 8% by mass of a carboxyl-group-containing ethylenically unsaturated monomer (a2), 0 to 40% by mass of a hydroxyl-group-containing ethylenically unsaturated monomer (a3), and 99 to 22% by mass of another ethylenically unsaturated monomer (a4) to solution polymerization in a multi-stage which includes two or more stages.

  本发明的目的是提供一种防污涂料树脂分散体，该分散体在海水中具有优异的贮存稳定性和耐水性，可长期显示防污效果，并具有自抛光性能和优异的粘附性。根据本发明生产防污涂料树脂分散体的方法包括以下步骤：生产含有二价金属的聚合物（A）；将聚合物（A）分散在含有水或水与有机溶剂混合物的分散介质中。含二价金属的聚合物(A)是通过以下方法获得的：1-40%（质量）的含二价金属的乙烯基不饱和单体(a1)，0-8%（质量）的含羧基的乙烯基不饱和单体(a2)、0 至 40%（质量百分比）的含羟基的乙烯基不饱和单体（a3）和 99 至 22%（质量 百分比）的另一种乙烯基不饱和单体（a4）进行溶液聚合。
• ANTIFOULING COATING COMPOSITION, METHOD FOR PRODUCING ANTIFOULING COATING FILM, AND ANTIFOULING COATING FILM
  申请人：Mitsubishi Rayon Co., Ltd.

  公开号：EP2557131A1

  公开（公告）日：2013-02-13

  The present invention provides an antifouling paint composition, by which a paint film can be formed using a small amount of an organic solvent, in which the strength and the self-abradability can be maintained for a long period, and by which a paint film having an excellent antifouling property can be formed. The antifouling paint composition according to the present invention contains an acrylic polymer (P), a radical polymerizable monomer (M) and an organic peroxide (O), wherein at least one of the acrylic polymer (P) and the radical polymerizable monomer (M) has a bivalent metal ester structure.

  本发明提供了一种防污漆组合物，通过该组合物可以使用少量有机溶剂形成漆膜，在漆膜中可以长期保持强度和自降解性，并且可以形成具有优异防污性能的漆膜。根据本发明的防污漆组合物含有丙烯酸聚合物（P）、可自由基聚合的单体（M）和有机过氧化物（O），其中丙烯酸聚合物（P）和可自由基聚合的单体（M）中至少有一种具有二价金属酯结构。
• POLYMER, RESIN COMPOSITION, ANTIFOULING COATING MATERIAL COMPOSITION, METHOD FOR PRODUCING POLYMER, METHOD FOR FORMING STRUCTURE FOR STABILIZING CARBAMATE ON SURFACE OF COATING FILM, AND METHOD FOR REGENERATING STRUCTURE FOR STABILIZING CARBAMATE ON SURFACE OF COATING FILM
  申请人：Waseda University

  公开号：EP3546487A1

  公开（公告）日：2019-10-02

  Provided are a polymer, a resin composition, and an antifouling coating material composition which are capable of forming a coating film having both of water resistance and antifouling properties resulting from superhydrophilicity; a method for producing the polymer; a method for forming a structure for stabilizing a carbamate on a surface of a coating film using the polymer; and a method for regenerating a structure for stabilizing a carbamate on a surface of a coating film using the polymer. The polymer having a structure which reacts with CO2 in the presence of water and stabilizes a formed carbamate, in which Expression (1) is satisfied. ContactangleinwaterafterreactionwithCO2−contactangleinwaterbeforereactionwithCO2≥10

  本发明提供了一种聚合物、一种树脂组合物和一种防污涂层材料组合物，它们能够形成同时具有由超亲水性产生的耐水性和防污性的涂膜；一种生产该聚合物的方法；一种使用该聚合物在涂膜表面形成用于稳定氨基甲酸酯的结构的方法；以及一种使用该聚合物在涂膜表面再生用于稳定氨基甲酸酯的结构的方法。该聚合物具有在水中与二氧化碳反应并稳定所形成的氨基甲酸酯的结构，其中表达式（1）得到满足。与 CO2 反应后水中的接触角与 反应前水中的接触角≥10