| 55101-35-4

• 分子结构分类: 有机化合物 - 碳氢化合物 - 饱和烃
• CAS: 55101-35-4
• 化学式: C₁₁H₂₃
• 分子量: 155.304
• InChiKey: QRPTVJPFFBTFSF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  11
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.91
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  马来酸酐 、 、 二苯二硫醚 、 alkaline earth salt of/the/ methylsulfuric acid 以 乙腈 为溶剂， 反应 10.0h， 生成 (3R,4S)-3-(1-Methyl-decyl)-4-phenylsulfanyl-dihydro-furan-2,5-dione 、 (3S,4R)-3-(1-Methyl-decyl)-4-phenylsulfanyl-dihydro-furan-2,5-dione
  参考文献：
  名称：

  钴肟介导的丁酸内酯自由基途径

  摘要：

  烷基钴肟与马来酸酐和PhSSPh的光解反应通过自由基烯烃的加成和随后的PhSSPh捕集进行。可以将产物反式3-苯硫基4-烷基琥珀酸酐通过氧化和热同步消除而转化为3-取代的马来酸酐，已知该3-取代的马来酸酐被区域选择性地和化学选择性地还原以产生γ-羟基丁烯内酯或丁烯内酯。

  DOI：

  10.1016/s0040-4039(00)61501-0
• 作为产物：
  描述：

  十一烷 在 C₁₀D₂₂ 作用下， 生成
  参考文献：
  名称：

  缺陷在结晶有机材料的辐射化学中的作用。2. ESR光谱法研究CmH2m + 2 / C10D22正构烃混合晶体辐射解产物中溶质自由基的有效选择性形成及其对碳链差异的依赖性

  摘要：

  DOI：

  10.1021/j100364a070

文献信息

• A study of alkyl radicals in the matrix of polycrystallinen-alkane γ-irradiated at 77 K
  作者：S. R. Allayarov、I. M. Barkalov

  DOI：10.1007/bf02494889

  日期：2000.6

  (T)he composition of alkyl radicals (AR) formed by gamma-radiolysis ( T = 77 K) of polycrystalline n-alkanes with different lengths of the carbon chain (C(5), C(7), C(10), C(11), and C(18)) and their polymeric analog (polyethylene) was estimated from the ESR spectra. The ESR spectra of the irradiated n-alkanes are superpositions of the signals from the (H3CCHCH2similar to)-H-. and similar to (CH2CHCH2similar to)-H-. radicals, whose HFS constants with alpha and beta protons as well as the equilibrium conformation are independent of the chain length of the n-alkane molecule. A dependence of the concentration of the radicals on the chain length of n-alkane was found. The absence of the similar to (CH2CH2)-H-. radicals that may arise upon H atom elimination from the Me fragments of the n-alkane molecules is most likely related to the transfer of excitation energy from the Me group to the neighboring methylene fragment and the transformation of the similar to (CH2CH2)-H-. radicals into (H3CCHCH2similar to)-H-. radicals. With account for this, the concentrations of the AR formed were suggested to be proportional to the number of H atoms at the corresponding C atom.