4,4'-二正十二烷氧基氧化偶氮苯 | 2312-14-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 中文名称: 4,4'-二正十二烷氧基氧化偶氮苯
• 英文名称: p,p'-Di-dodecyloxy-azoxybenzol
• 英文别名: 4,4'-Didodecyloxy-azoxybenzol；4,4'-Didodecyloxyazoxybenzene；(4-dodecoxyphenyl)-(4-dodecoxyphenyl)imino-oxidoazanium
• CAS: 2312-14-3
• 化学式: C₃₆H₅₈N₂O₃
• mdl: MFCD00059283
• 分子量: 566.868
• InChiKey: RFLXFGRPXYHTKL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  14.3
• 重原子数：
  41
• 可旋转键数：
  26
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.666
• 拓扑面积：
  59.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  溴代十二烷 在 氢化铋 、 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 3.0h， 生成 4,4'-二正十二烷氧基氧化偶氮苯
  参考文献：
  名称：

  The Newborn Surface of Dull Metals in Organic Synthesis. Bismuth-Mediated Solvent-Free One-Step Conversion of Nitroarenes to Azoxy- and Azoarenes

  摘要：

  When milled together with bismuth shots, nitroarenes are readily converted to azoxy- and/or azoarenes depending on substrates and conditions employed. Simple extraction with organic solvent followed by evaporation of the resulting dark pasty solid gave the product in good yield.

  DOI：

  10.1021/jo0203645

文献信息

• Electrically conductive liquid crystalline substance and polymer
  申请人：SHOWA DENKO KABUSHIKI KAISHA

  公开号：EP0106175A2

  公开（公告）日：1984-04-25

  An electrically conductive liquid crystalline substance represented by the general formula L-S1-CT or L-CT, wherein L is a residue of a liquid crystalline substance, S, is an atom or atomic grouping which becomes a spacer and CT is a charge-transfer complex, is disclosed. An electrically conductive liquid crystalline polymer having an electrically conductive liquid crystalline substance portion in its side chain is also provided. These electrically conductive liquid crystalline materials are useful in the conventional applications of liquid crystals and in other applications which utilize their electrical conductivity.

  本发明公开了一种由通式 L-S1-CT 或 L-CT 表示的导电液晶物质，其中 L 是液晶物质的残基，S 是成为间隔物的原子或原子团，CT 是电荷转移复合物。此外，还提供了一种导电液晶聚合物，其侧链中具有导电液晶物质部分。这些导电液晶材料适用于液晶的传统应用以及利用其导电性的其他应用。
• US4657694A
  申请人：——

  公开号：US4657694A

  公开（公告）日：1987-04-14
• US4769448A
  申请人：——

  公开号：US4769448A

  公开（公告）日：1988-09-06
• The Newborn Surface of Dull Metals in Organic Synthesis. Bismuth-Mediated Solvent-Free One-Step Conversion of Nitroarenes to Azoxy- and Azoarenes
  作者：Shinobu Wada、Mika Urano、Hitomi Suzuki

  DOI：10.1021/jo0203645

  日期：2002.11.1

  When milled together with bismuth shots, nitroarenes are readily converted to azoxy- and/or azoarenes depending on substrates and conditions employed. Simple extraction with organic solvent followed by evaporation of the resulting dark pasty solid gave the product in good yield.