(OC)3Mo(η6-C7H7-C7H7-η6)Mo(CO)3 | 53556-08-4

• 分子结构分类: 有机化合物 - 碳氢化合物 - 多环烃
• 英文名称: (OC)3Mo(η6-C7H7-C7H7-η6)Mo(CO)3
• 英文别名: carbon monoxide;7-cyclohepta-2,4,6-trien-1-ylcyclohepta-1,3,5-triene;molybdenum
• CAS: 53556-08-4；118016-05-0；118016-04-9；118016-06-1
• 化学式: C₂₀H₁₄Mo₂O₆
• 分子量: 542.208
• InChiKey: DPSJEYCTLUZQBY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  (OC)3Mo(η6-C7H7-C7H7-η6)Mo(CO)3 、 bis(triphenylphosphoranylidene)ammonium bromide 在 potassium naphtalenide 作用下， 以 四氢呋喃 为溶剂， 生成 [(Mo(CO)3)2(μ-.eta(5):η(5)-C7H7C7H7)][PPN]2
  参考文献：
  名称：

  所述鎓环的环二聚通过还原[（η 7 -C 7 ħ 7）的Mo（CO）3 ] +，得到[{沫（CO）3 } 2（μ-η 5：η 5 -C 7 ħ 7 - C 7 H 7）] [PPN] 2

  摘要：

  在卓鎓环的还原活化[（η 7 -C 7 ħ 7）M（CO）3 ] BF 4（M =铬，钼，W）导致环二聚和形成[{M（CO）3 } 2（ μ-η 5：η 5 -C 7 ħ 7 -C 7 ħ 7）] [PPN] 2，将其分离并表征为M =钼，并且也通过还原中性二聚体的形成[{沫（CO）3 } 2（η 6：η 6 -C 7 ħ 7 -C 7 ħ7）]。铬和钨类似物通过光谱鉴定。

  DOI：

  10.1021/om9606909
• 作为产物：
  描述：

  生成 (OC)3Mo(η6-C7H7-C7H7-η6)Mo(CO)3
  参考文献：
  名称：

  Niemer, Burkhard; Breimair, Josef; Voelkel, Thomas, Chemische Berichte, 1991, vol. 124, # 10, p. 2237 - 2244

  摘要：

  DOI：

文献信息

• Metallorganische Lewis-Säuren
  作者：Josef Breimair、Christian Robl、Wolfgang Beck

  DOI：10.1016/0022-328x(91)83045-6

  日期：1991.7

  [η2-C2H4)Re(CO)5]+PF6− reacts with the highly reduced Ellis compound na3Ir(CO)3 to give the linear, trinuclear hydride (OC)5Re-Ir(CO)3H-Re(CO)5 (1), the structure of which has been determined by X-ray diffraction. Unexpectedly, from a solution of [(η2-C2H4)Re(CO)5]+ and [Ir(CO)3]3− exposed to air, crystals have been obtained which contain the carbonate bridged complex (μ3-CO3)[Re(CO)5]3+ReO4− (3) of wind

  阳离子络合物[η 2 -C 2 H ^ 4）的Re（CO）5 ] + PF 6 -与该高度还原埃利斯化合物发生反应NA 3的Ir（CO）3，得到直链的，三核氢化物（OC）5重新铱（CO）3 H-Re（CO）5（1），其结构已通过X射线衍射确定。出乎意料的是，从溶液[（η 2 -C 2 H ^ 4）的Re（CO）5 ] +和物[Ir（CO）3 ] 3-暴露于空气中，已获得的晶体含有碳酸酯桥连的络合物（μ 3 -CO 3）[重（CO）5 ] 3 + REO 4 - （3）的风轮结构和已知的立方烷[的Re（CO）3 OH] 4（2在单元电池。[的Re（CO）的反应4 ] 3-和[（μ 7 -C 7 ħ 7）的Mo（CO）3 ] +，得到氧化还原产物（OC）3的Mo（μ 6 -C 7 H 7 -C7 ħ 7 -μ 6）的Mo（CO）3（4）。
• Heterometallic analogues of [{M(CO)2(η-C5H5)}2] (M = Fe, Ru, Os). The synthesis of the tetracarbonylcyclopentadienylcycloheptatrienyl complexes [M(CO)2(η-C5H5)M′(CO)2(η-C7H7)] (M = Fe, Ru; M′ = Mo, W). Crystal structures of [Ru(CO)2(η-C5H5Mo(CO)2(η-C7H7)] (RuMo) and [Mo(CO)3(μ-η6, η1-C7H7)Ru(CO)2(η-C5Me5)]
  作者：Roy L. Beddoes、E.Stephen Davies、Madeleine Helliwell、Mark W. Whiteley

  DOI：10.1016/0022-328x(91)86413-k

  日期：1991.12

  The heterobimetallic, metalmetal-bonded complexes [M(CO)2(η-C5H5)M′(CO)2(η-C7H7)] (1, M = Ru, M′ = Mo; 2, M = Fe, M′ = Mo; 3, M = Ru, M′ = W) have been synthesised by reaction of Na[M(CO)2(η-C5H5)] with [M′Br(CO)2(η-C7H7)]. The X-ray crystal structure of 1 reveals an unsupported RuMo bond length of 2.952(1) Å and a cis arrangement of C5H5 and C7H7 rings, but solution infrared studies suggest a solvent-dependent

  所述的异，metalmetal键合的配合物[M（CO）2（η-C 5 H ^ 5）M'（CO）2（η-C 7 H ^ 7）]（1，M = RU，M'=沫; 2，M =铁，M'=沫; 3，M = RU，M'= W）已经被Na [M（CO）的反应合成的2（η-C 5 H ^ 5）]与[M'Br（ CO）2（η-C 7 H ^ 7）]。的X射线晶体结构1揭示的2.952（1）不支持的RuMo键长和一个顺式的C排列5 ħ 5和C7 H 7环，但溶液红外研究表明其依赖溶剂。的治疗[MoBr（CO）2（η-C 7 H ^ 7）]具有K的[Ru（CO）2（η-C 5我5）]给出的[Ru（CO）2（η-C 5我5的Mo（ CO）2（η-C 7 H ^ 7）]（4）在非常低的产率的主要产物，环庚三烯基桥连[沫（CO）一起3（μ-η 6，η 1 -C 7 ħ 7）的Ru（ CO）2（η-C 5Me 5）]（5），其在结晶学上已表征。
• Ditropylmolybdenum complexes by the sodium reduction of [Mo(CO)3(η-C7H7)][BF4]. X-Ray crystal structure of the ditropyl complex “Mo(CO)3”2(η6,η′6-C14H14)
  作者：Harry Adams、Neil A. Bailey、David G. Willett、Mark J. Winter

  DOI：10.1016/s0022-328x(00)99031-4

  日期：1987.10

  Treatment of [Mo(CO)3(η-C7H7)][BF4] with either sodium amalgam or sodium naphthalide results in a reductive dimerisation to the ditropyl complex “Mo(CO)3”2(η6,η′6-C14H14). The results of an X-ray crystallographic study confirm that the hydrogen atoms of the linking carbon atoms are both endo with respect to molybdenum. The reaction of Mo(CO)6 with ditropyl, C14H14, leads to all three possible isomers

  [沫（CO）的治疗3（η-C 7 H ^ 7）] [BF 4 ]与在还原二聚到ditropyl复合物“的Mo（CO）或者钠汞齐或萘基钠结果3 ” 2（η 6，η ′ 6 -C 14 H 14）。X射线晶体学研究的结果证实，连接的碳原子的氢原子都相对于钼是内在的。Mo（CO）6与对苯二酚C 14 H 14的反应生成“ Mo（CO）3 ” 2（η6，η' 6 -C 14 -H 14）。每种的结构由其1 H NMR谱确定。
• Olgemoeller, Bernhard; Beck, Wolfgang, Chemische Berichte, 1981, vol. 114, # 3, p. 867 - 876
  作者：Olgemoeller, Bernhard、Beck, Wolfgang

  DOI：——

  日期：——
• Synthesis and X-ray crystal structure of the dimolybdenum acetaldehyde complex [Mo₂(η-MeCHO)(CO)₄(η-C₅H₅)₂]
  作者：Harry Adams、Neil A. Bailey、J. Trevor Gauntlett、Mark J. Winter、Simon Woodward

  DOI：10.1039/dt9910002217

  日期：——

  The reaction of [Mo(MeCHO)(CO)2(eta-C5H5)]- 1 with [C7H7][BF4] gives the three organometallics [Mo2(mu-eta-2-MeCHO)(CO)4(eta-C5H5)2] 2, [Mo(CO)3(eta-C5H5)}] and [Mo(CO)2(eta-3-C7H7)(eta-C5H5)], the first of which has been characterised by X-ray crystallography [monoclinic, space group P2(1)/c, a = 8.265(4), b = 15.191(3), c = 13.511(9) angstrom, beta = 97.89(5)-degrees, R 0.0362 for 2104 independent reflections for which l/sigma(l) > 3.0]. The molecule consists of two Mo(CO)2(eta-C5H5) groups linked by a Mo-Mo bond [2.9670(8) angstrom] and bridged by an acetaldehyde ligand (eta-2 through both C and O to one metal atom, sigma through the oxygen to the second metal). The same three products arise in the reaction of 1 with [Mo(CO)3(eta-C7H7)][BF4], together with [Mo(CO)3(eta-6-C7H7)}2]. Addition of LiBEt3H to [Mo2(mu-eta-2-MeCO)(CO)4(eta-C5H5)2]BF4 gives a high yield of 2, as does the reaction of HBF4.OEt2 with 1. The reactions of complex 1 with any of (CF3CO)2O, HC = CCH2Br, PhCH2Br, [M(CO)3(eta-C5H5)][BF4] (M = Mo or W), CH2Cl2, [Fe(eta-C5H5)2][PF6] and Fe2(SO4)3 lead to low yields of 2. The tungsten complex [W2(mu-eta-2-MeCHO)(CO)4(eta-C5H5)2] is produced in low yield in the reaction of Li[W(H)(COMe)(CO)2(eta-C5H5)] with HBF4.OEt2.