trans-tetrakis(1-tert-butyl-imidazole-2-thiolate)dinickel(II) | 1192013-17-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: trans-tetrakis(1-tert-butyl-imidazole-2-thiolate)dinickel(II)
• CAS: 1192013-17-4
• 化学式: C₂₈H₄₄N₈Ni₂S₄
• 分子量: 738.355
• InChiKey: DSTHWBSFNUGLKT-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (2-mercapto-1-tert-butylimidazolate)bis(trimethylphosphine)nickel(II) 在 (C₆H₅C(O)O)2 作用下， 以 苯 为溶剂， 生成 trans-tetrakis(1-tert-butyl-imidazole-2-thiolate)dinickel(II)
  参考文献：
  名称：

  2-Mercapto-1-t-butylimidazolyl as a bridging ligand: Synthesis and structural characterization of nickel and palladium paddlewheel complexes

  摘要：

  Nickel and palladium paddlewheel complexes that feature 2-mercapto-1-t-butylimidazolyl (mim(But)) bridging ligands, namely Ni-2[mim(But)](4) and Pd-2[mim(But)](4), have been synthesized and structurally characterized by X-ray diffraction. Since the mimBut ligand bridges in an asymmetric manner via a sulfur and nitrogen donor, paddlewheel compounds of the type M-2[mim(But)](4) may exist as isomers that are distinguished by the relative orientations of the ligands. In this regard, the (4,0)-Ni-2[mim(But)](4) and trans-(2,2)-Ni-2[mim(But)](4) isomers have been isolated for the nickel system, while the (4,0)-Pd-2[mim(But)](4) and (3,1)-Pd-2[mim(But)](4) isomers have been isolated for the palladium system. (C) 2009 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.05.025