aqua(saccharinate)(2,2':6',6''-terpyridie)nickel(II) saccharinate monohydrate | 1021296-98-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯并吡啶类
• 英文名称: aqua(saccharinate)(2,2':6',6''-terpyridie)nickel(II) saccharinate monohydrate
• CAS: 1021296-98-9
• 化学式: C₇H₄NO₃S*C₂₂H₁₉N₄NiO₅S*H₂O
• 分子量: 710.368
• InChiKey: WCOMVIULLXLNKO-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  α,α,α-三联吡啶 、 水 、 tetraaquabis(saccharinato)nickel(II) dihydrate 以 水 为溶剂， 生成 aqua(saccharinate)(2,2':6',6''-terpyridie)nickel(II) saccharinate monohydrate
  参考文献：
  名称：

  Synthesis and structural characterisation of four saccharinate – Metal complexes with 2,2′:6,2″-terpyridine (terpy) as a co-ligand

  摘要：

  Four saccharinate complexes of divalent transition metals with 2,2': 6,2"-terpyridine (terpy) as a co-ligand have been synthesised, and characterised by elemental analysis and single crystal X-ray diffraction at low temperature. The complexes [M( terpy)( sac)( H2O) 2] sac H2O (1, M = Mn; 2, M = Co; 3, M = Ni) are isostructural, crystallising in space group Pbca. The metal ions have approximately octahedral coordination, with the two coordinated water molecules occupying cis-positions. These water molecules are hydrogen-bonded to the oxygen atom in the free water molecule. The copper(II) ion in the anhydrous complex [Cu( terpy)( sac)(2) ] 4 is five-coordinate; the compound crystallises in the space group P2(1)/c. (c) 2007 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2007.09.019