Caesiumcarbazolat | 73689-66-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: Caesiumcarbazolat
• CAS: 73689-66-4
• 化学式: C₁₂H₈N*Cs
• 分子量: 299.108
• InChiKey: ZWKBGVRQWNFJBI-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  咔唑 、 Caesiumcarbazolat 以 四氢呋喃 为溶剂， 生成 cesium carbazide - carbazole 1: 1 complex
  参考文献：
  名称：

  Ion Pair Properties of Lithium and Cesium Salts of Carbazole¹

  摘要：

  The lithium salt of carbazole, LiCb, is monomeric in THF in the concentration range (1-5) x 10(-3) M. It is a contact ion pair (CIP) with an effective ion pair pK of 13.48 on a scale where fluorenyllithium solvent separated ion pairs (SSIP) are 22.90 (per hydrogen). The cesium salt, CsCb, is a mixture of monomer and dimer with K-2 = 300 M-1. The monomer forms a 1:1 complex, CsCb . CbH, with K-c = 62 M-1. The ion pair pK of monomeric CsCb is 19.24.

  DOI：

  10.1021/ja972839t
• 作为产物：
  描述：

  cesium carbazide - carbazole 1: 1 complex 以 四氢呋喃 为溶剂， 生成 咔唑 、 Caesiumcarbazolat
  参考文献：
  名称：

  Ion Pair Properties of Lithium and Cesium Salts of Carbazole¹

  摘要：

  The lithium salt of carbazole, LiCb, is monomeric in THF in the concentration range (1-5) x 10(-3) M. It is a contact ion pair (CIP) with an effective ion pair pK of 13.48 on a scale where fluorenyllithium solvent separated ion pairs (SSIP) are 22.90 (per hydrogen). The cesium salt, CsCb, is a mixture of monomer and dimer with K-2 = 300 M-1. The monomer forms a 1:1 complex, CsCb . CbH, with K-c = 62 M-1. The ion pair pK of monomeric CsCb is 19.24.

  DOI：

  10.1021/ja972839t