((diphenylstannanediyl)bis(methylene))bis(diphenylphosphine sulfide) | 156700-73-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: ((diphenylstannanediyl)bis(methylene))bis(diphenylphosphine sulfide)
• CAS: 156700-73-1
• 化学式: C₃₈H₃₄P₂S₂Sn
• 分子量: 735.477
• InChiKey: WYSKEGYBGWFAIH-UHFFFAOYSA-N

物化性质

• 沸点：
  747.1±70.0 °C(predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.59
• 重原子数：
  43.0
• 可旋转键数：
  10.0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  (tetrahydrothiophene)gold(I) chloride 、 ((diphenylstannanediyl)bis(methylene))bis(diphenylphosphine sulfide) 以 not given 为溶剂， 生成
  参考文献：
  名称：

  Syntheses and characterizations of tin complexes of methylenediphenylphosphinate ligands: the crystal structures of [Ph4−xSn(CH2P(S)Ph2)x] (x = 1–4) and [Ph2SnCl(CH2P(O)Ph2)]2

  摘要：

  Reactions between methylenediphenylphosphinate anions [CH2P(E)Ph2]-(E = S, O) and appropriate chlorophenyltin(IV) compounds in tetrahydrofuran afforded the organotin compounds [Ph4-xSn(CH2P(S)Ph2)x], (x = 1-4), 1-4 and [Ph2SnCl(CH2 P(O)Ph2)]2, 5. All compounds have been characterized structurally, 1-4 as 4-coordinate monometallic species and 5 as a bimetallic 8-membered metallacycle which is 5-coordinate at each metal atom.

  DOI：

  10.1016/s0277-5387(00)80101-1
• 作为产物：
  描述：

  lithium,methanidyl-diphenyl-sulfanylidene-λ⁵-phosphane 、 二苯基二氯化锡 以 四氢呋喃 、 乙醚 为溶剂， 以66%的产率得到((diphenylstannanediyl)bis(methylene))bis(diphenylphosphine sulfide)
  参考文献：
  名称：

  Syntheses and characterizations of tin complexes of methylenediphenylphosphinate ligands: the crystal structures of [Ph4−xSn(CH2P(S)Ph2)x] (x = 1–4) and [Ph2SnCl(CH2P(O)Ph2)]2

  摘要：

  Reactions between methylenediphenylphosphinate anions [CH2P(E)Ph2]-(E = S, O) and appropriate chlorophenyltin(IV) compounds in tetrahydrofuran afforded the organotin compounds [Ph4-xSn(CH2P(S)Ph2)x], (x = 1-4), 1-4 and [Ph2SnCl(CH2 P(O)Ph2)]2, 5. All compounds have been characterized structurally, 1-4 as 4-coordinate monometallic species and 5 as a bimetallic 8-membered metallacycle which is 5-coordinate at each metal atom.

  DOI：

  10.1016/s0277-5387(00)80101-1