3-(methacryloyloxy)-2,2,4,4-tetramethylcyclobutyl 3-oxobutanoate | 1381948-47-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 3-(methacryloyloxy)-2,2,4,4-tetramethylcyclobutyl 3-oxobutanoate
• 英文别名: [2,2,4,4-tetramethyl-3-(2-methylprop-2-enoyloxy)cyclobutyl] 3-oxobutanoate
• CAS: 1381948-47-5
• 化学式: C₁₆H₂₄O₅
• 分子量: 296.364
• InChiKey: BSESQQMFKGYYCS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  21
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.69
• 拓扑面积：
  69.7
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  3-(methacryloyloxy)-2,2,4,4-tetramethylcyclobutyl 3-oxobutanoate 在 水 作用下， 反应 96.0h， 生成 3-hydroxy-2,2,4,4-tetramethylcyclobutyl methacrylate 、 丙酮
  参考文献：
  名称：

  [EN] ACETOACETATE-FUNCTIONAL MONOMERS AND THEIR USES IN COATING COMPOSITIONS
  [FR] MONOMÈRES À FONCTION ACÉTOACÉTATE ET LEURS UTILISATIONS DANS DES COMPOSITIONS DE REVÊTEMENT

  摘要：

  披露了对应于以下公式1的乙酰乙酸酯官能单体：其中R为氢或甲基基团；X为具有5至8个碳原子的支链烷基或支链环烷基；Y1和Y2独立地为氢或甲基。还披露了包含来自公式1的乙酰乙酸酯官能单体残基和一个或多个额外的乙烯基不饱和单体的乳液、悬浮液和溶液聚合物。同样披露了包含公式1的乙酰乙酸酯官能单体的自固化涂层组合物，以及可选地一个或多个额外的乙烯基不饱和单体。还披露了包含具有来自公式1的乙酰乙酸酯官能单体残基的聚合物分散在可挥发水载体中的乳胶配方。

  公开号：

  WO2012082348A1
• 作为产物：
  描述：

  2,2,4,4-四甲基-1,3-环丁二醇 在 4-二甲氨基吡啶 、 高效阻聚剂N-NO 作用下， 以 四氢呋喃 、 二氯甲烷 为溶剂， 反应 6.0h， 生成 3-(methacryloyloxy)-2,2,4,4-tetramethylcyclobutyl 3-oxobutanoate
  参考文献：
  名称：

  [EN] ACETOACETATE-FUNCTIONAL MONOMERS AND THEIR USES IN COATING COMPOSITIONS
  [FR] MONOMÈRES À FONCTION ACÉTOACÉTATE ET LEURS UTILISATIONS DANS DES COMPOSITIONS DE REVÊTEMENT

  摘要：

  披露了对应于以下公式1的乙酰乙酸酯官能单体：其中R为氢或甲基基团；X为具有5至8个碳原子的支链烷基或支链环烷基；Y1和Y2独立地为氢或甲基。还披露了包含来自公式1的乙酰乙酸酯官能单体残基和一个或多个额外的乙烯基不饱和单体的乳液、悬浮液和溶液聚合物。同样披露了包含公式1的乙酰乙酸酯官能单体的自固化涂层组合物，以及可选地一个或多个额外的乙烯基不饱和单体。还披露了包含具有来自公式1的乙酰乙酸酯官能单体残基的聚合物分散在可挥发水载体中的乳胶配方。

  公开号：

  WO2012082348A1

文献信息

• ACETOACETATE-FUNCTIONAL MONOMERS AND THEIR USES IN COATING COMPOSITIONS
  申请人：Maddox John Thorton

  公开号：US20120157610A1

  公开（公告）日：2012-06-21

  Acetoacetate-functional monomers are disclosed that correspond to the following formula 1: in which R is hydrogen, or a methylgroup; X is a branched alkyl or a branched cyclic alkyl having from 5 to 8 carbon atoms; and Y1 and Y2 are independently hydrogen or methyl. Also disclosed are emulsion, suspension, and solution polymers comprising residues from the acetoacetate-functional monomer of formula 1 and one or more additional ethylenically unsaturated monomers. Self-curing coating compositions are likewise disclosed that comprise the acetoacetate-functional monomer of formula 1, and optionally one or more additional ethylenically unsaturated monomers. Latex formulations are also disclosed that comprise a polymer having residues from the acetoacetate-functional monomer of formula 1 dispersed in an evaporable aqueous carrier.

  揭示了与以下公式1对应的乙酰丙酮酸功能单体：其中R是氢或甲基基团；X是具有5至8个碳原子的支链烷基或支链环烷基；Y1和Y2独立地是氢或甲基。还揭示了包含来自公式1中乙酰丙酮酸功能单体残基的乳液、悬浮液和溶液聚合物，以及一个或多个额外的乙烯基不饱和单体。同样揭示了自固化涂层组合物，其中包括公式1中的乙酰丙酮酸功能单体，以及一个或多个额外的乙烯基不饱和单体。还揭示了乳胶配方，其中包括在可挥发水载体中分散的具有来自公式1中乙酰丙酮酸功能单体残基的聚合物。
• Acetoacetate-functional monomers and their uses in coating compositions
  申请人：Maddox John Thorton

  公开号：US08809447B2

  公开（公告）日：2014-08-19

  Acetoacetate-functional monomers are disclosed that correspond to the following formula 1: in which R is hydrogen, or a methylgroup; X is a branched alkyl or a branched cyclic alkyl having from 5 to 8 carbon atoms; and Y1 and Y2 are independently hydrogen or methyl. Also disclosed are emulsion, suspension, and solution polymers comprising residues from the acetoacetate-functional monomer of formula 1 and one or more additional ethylenically unsaturated monomers. Self-curing coating compositions are likewise disclosed that comprise the acetoacetate-functional monomer of formula 1, and optionally one or more additional ethylenically unsaturated monomers. Latex formulations are also disclosed that comprise a polymer having residues from the acetoacetate-functional monomer of formula 1 dispersed in an evaporable aqueous carrier.

  本文披露了与以下公式1相对应的乙酰乙酸酯官能单体：其中R为氢或甲基基团；X为分支烷基或分支环烷基，具有5至8个碳原子；Y1和Y2独立地为氢或甲基。本文还披露了乳液、悬浮液和溶液聚合物，其中包括来自公式1的乙酰乙酸酯官能单体的残基和一个或多个额外的乙烯基不饱和单体。本文还披露了自固化涂料组合物，其中包括公式1的乙酰乙酸酯官能单体，以及可选的一个或多个额外的乙烯基不饱和单体。本文还披露了乳胶配方，其中包括在可挥发的水载体中分散的具有来自公式1的乙酰乙酸酯官能单体残基的聚合物。
• US8809447B2
  申请人：——

  公开号：US8809447B2

  公开（公告）日：2014-08-19
• [EN] POLYMER LATEX<br/>[FR] LATEX POLYMÈRE
  申请人：SYNTHOMER SDN BHD

  公开号：WO2022010341A1

  公开（公告）日：2022-01-13

  The present invention relates to a polymer latex comprising: (A) particles of a latex polymer (A) obtainable by free-radical emulsion polymerization of a mixture of ethylenically unsaturated monomers the latex polymer comprising a plurality of functional groups (x); and (B) a compound bearing a beta-hydroxy ester linkage and at least one additional functional group (y) reactive with the functional groups (x) on latex polymer (A), to a method for preparation of said polymer latex, to its use, to a method for dip-molding and to articles obtained from the latex.
• [EN] POLYMER LATEX COMPOSITION<br/>[FR] COMPOSITION DE LATEX DE POLYMÈRE
  申请人：[en]SYNTHOMER SDN BHD

  公开号：WO2022216149A1

  公开（公告）日：2022-10-13

  The present invention relates to a polymer latex composition, to a method for the preparation of such polymer latex composition, to a compounded latex composition comprising said polymer latex composition, to the use of said polymer latex composition, to a method for making dip-molded articles, to a method for the production of a continuous elastomeric film and for making an elastomeric article, to a method for repairing or reforming an elastomeric film or an article and to articles made by using said polymer latex composition.