3,3-bis(4-methoxyphenyl)-13,13-dimethyl-3H,13H-indeno[2',3':3,4]naphtho[1,2-b]pyran | 912341-20-9

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 黄酮类化合物
• 英文名称: 3,3-bis(4-methoxyphenyl)-13,13-dimethyl-3H,13H-indeno[2',3':3,4]naphtho[1,2-b]pyran
• 英文别名: 3,3-di(4-methoxyphenyl)-13,13-dimethyl-3H,13H-benz[p]indeno[2',3':3,4]naphtho[1,2-b]pyran；3,3-bis(4-methoxyphenyl)-13,13-dimethyl-3H,13H-indeno[2',1':3,4]naphtho[1,2-b]pyran；5,5-Bis(4-methoxyphenyl)-21,21-dimethyl-6-oxapentacyclo[12.7.0.02,7.08,13.015,20]henicosa-1(14),2(7),3,8,10,12,15,17,19-nonaene
• CAS: 912341-20-9
• 化学式: C₃₆H₃₀O₃
• 分子量: 510.632
• InChiKey: VAUDSXPKVOEUNI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.1
• 重原子数：
  39
• 可旋转键数：
  4
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  3

文献信息

• [EN] PHOTOCHROMIC COMPOUNDS AND COMPOSITIONS<br/>[FR] COMPOSÉS ET COMPOSITIONS PHOTOCHROMES
  申请人：TRANSITIONS OPTICAL INC

  公开号：WO2012082999A1

  公开（公告）日：2012-06-21

  Described herein are compounds (III) comprising an indeno[2',3', 3, 4] naptho [1,2-b] pyran structure. Such compounds may be useful for their photochromic properties, and be use in certain photochromic compositions. Such compositions may further comprise other photochromic compositions and/or materials. Additionally, such compounds and/or compositions may be suitable for preparing certain photochromic articles.

  本文描述了包含吲哚并[2'，3'，3，4]萘[1,2-b]吡喃结构的化合物（III）。这些化合物可能因其光致变色性能而有用，并可用于某些光致变色组合物中。这些组合物可能进一步包括其他光致变色组合物和/或材料。此外，这些化合物和/或组合物可能适用于制备某些光致变色物品。
• [EN] SILOLE AND GERMOLE FUSED RING PHOTOCHROMIC COMPOUNDS<br/>[FR] COMPOSÉS PHOTOCHROMIQUES SILOLE ET GERMOLE À CYCLE FUSIONNÉ
  申请人：TRANSITIONS OPTICAL LTD

  公开号：WO2019001724A1

  公开（公告）日：2019-01-03

  The present invention relates to silole and germole fused ring photochromic compounds represented, with some embodiments, by the following Formula (Ia), (Ia) With reference to Formula (Ia): M includes Si or Ge; Ring A and Ring B each independently include aryl or heteroaryl; and the photochromic compound is a thermally reversible photochromic compound. The present invention also relates to photochromic compositions and photochromic articles, such as photochromic ophthalmic articles that include one or more photochromic compounds represented, with some embodiments, by Formula (Ia).

  本发明涉及硅杂环和锗杂环融合环光致变色化合物，其中一些实施例由以下式（Ia）表示，（Ia）参照式（Ia）：M包括Si或Ge；环A和环B各自独立地包括芳基或杂芳基；光致变色化合物是热可逆光致变色化合物。本发明还涉及光致变色组合物和光致变色物品，例如包括由式（Ia）表示的一个或多个光致变色化合物的光致变色眼科物品。
• PHOTOCHROMIC COMPOUNDS AND COMPOSITIONS
  申请人：He Meng

  公开号：US20120156508A1

  公开（公告）日：2012-06-21

  Described herein are compounds generally comprising an indeno[2′,3′:3,4]naptho[1,2-b]pyran structure. Such compounds may be useful for their photochromic properties, and be used in certain photochromic compositions. Such compositions may further comprise other photochromic compositions and/or materials. Additionally, such compounds and/or compositions may be suitable for preparing certain photochromic articles.

  本文描述的化合物通常包括一个吲哚并[2′,3′:3,4]萘并[1,2-b]吡喃结构。这些化合物可能因其光致变色性能而有用，并可用于某些光致变色组合物中。这样的组合物可能进一步包括其他光致变色组合物和/或材料。此外，这样的化合物和/或组合物可能适用于制备某些光致变色物品。
• METHODS FOR PRODUCING PHOTOSENSITIVE MICROPARTICLES
  申请人：Bowles Steven E.

  公开号：US20100221661A1

  公开（公告）日：2010-09-02

  Described are various methods of producing non-aqueous dispersions of photosensitive polymeric microparticles, comprising: (a) preparing one or more aqueous dispersions of a polymerizable component, at least one of which contains a photosensitive material and, wherein the polymerizable components comprise at least one hydrophilic functional group and/or at least one hydrophobic functional group; (b) subjecting the dispersion of (a) to conditions sufficient to form microparticles; (c) at least partially polymerizing the polymerizable component; (d) combining the dispersion with an organic continuous phase comprising an organic solvent; (e) removing water from the dispersion such that the final water content of the non-aqueous dispersion is less than 30 percent by weight; wherein e) is performed before or after d); and (f) reacting any acid functional groups on the surface of the microparticles with a reactive material having at least one epoxy functional group, at least one thiocarbonylthio functional group, at least one alkoxyamine functional group, or at least one halide functional group.

  本文描述了制备非水分散的光敏聚合微粒的各种方法，包括：(a)制备一种或多种聚合组分的水分散液，其中至少一种含有光敏材料，所述聚合组分包括至少一种亲水性功能基和/或至少一种疏水性功能基；(b)将(a)的分散液置于足以形成微粒的条件下；(c)至少部分聚合聚合组分；(d)将分散液与包含有机溶剂的有机连续相结合；(e)去除分散液中的水分，使得最终的非水分散液的水含量小于30重量％；其中e)在d)之前或之后执行；(f)用至少一种环氧功能基、至少一种硫代氨基酸功能基、至少一种烷氧胺功能基或至少一种卤素功能基的反应性材料反应微粒表面上的任何酸性功能基。
• PHOTOCHROMIC MATERIALS
  申请人：Tomasulo Massimiliano

  公开号：US20110108781A1

  公开（公告）日：2011-05-12

  The present invention relates to photochromic materials that include a photochromic compound that includes a photochromic substituent (e.g., an indeno-fused naphthopyran) and at least one pendent silane group, which is bonded to the photochromic substituent. The pendent silane groups are selected from certain pendent siloxy-silane groups and/or pendent alkoxy-silane groups represented by general formulas (I) and/or (II) as described in further detail herein. The present invention also relates to photochromic articles, such as photochromic optical elements (e.g., photochromic lenses), and photochromic coating compositions (e.g., curable photochromic coating compositions), that include the photochromic materials of the present invention. The photochromic materials of the present invention have improved compatibility with compositions into which they may be incorporated, for example, coating compositions, such as urethane coating compositions.

  本发明涉及包括具有光致变色取代基（例如，吲哚并环戊基吡喃）和至少一个侧基硅烷基的光致变色化合物的光致变色材料。侧基硅烷基从描述的通用式（I）和/或（II）表示的某些侧基硅氧烷基和/或侧基烷氧基中选择。本发明还涉及光致变色物品，例如光致变色光学元件（例如，光致变色透镜）和光致变色涂层组合物（例如，可固化的光致变色涂层组合物），其中包括本发明的光致变色材料。本发明的光致变色材料与可能加入其中的组合物（例如，涂层组合物，例如脲基涂层组合物）具有改进的相容性。