(R)-23-((S)-2,2-Dimethyl-[1,3]dioxan-4-yl)-tricosan-2-ol | 142922-44-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: (R)-23-((S)-2,2-Dimethyl-[1,3]dioxan-4-yl)-tricosan-2-ol
• CAS: 142922-44-9
• 化学式: C₂₉H₅₈O₃
• 分子量: 454.778
• InChiKey: NIYUXCJGGLICAD-IZLXSDGUSA-N

反应信息

• 作为反应物：
  描述：

  甲氧基-三氟甲基苯 、 (R)-23-((S)-2,2-Dimethyl-[1,3]dioxan-4-yl)-tricosan-2-ol 在 吡啶 、 4-二甲氨基吡啶 作用下， 反应 24.0h， 生成 (R)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid (R)-22-((S)-2,2-dimethyl-[1,3]dioxan-4-yl)-1-methyl-docosyl ester
  参考文献：
  名称：

  Structure of the “heterocyst glycolipids” of the marine cyanobacterium Nodularia harveyana

  摘要：

  The ''heterocyst glycolipids'' have been reported to take part in the protection of the specialized cyanobacterial cells capable of N2 fixation against the penetration Of O2. For the first time such glycolipids have been isolated in a pure form from a cyanobacterium, Nodularia harveyana, and their structures have been established by spectroscopic and chemical means to be 1-(O-alpha-D-glucopyranosyl)-3R,25R-hexacosanediol, 1-(O-alpha-D-glucopyranosyl)-3S,25R-hexacosanediol and 1-(O-alpha-D-glucopyranosyl)-3-keto-25R-hexacosanol.

  DOI：

  10.1016/s0040-4020(01)89033-5
• 作为产物：
  描述：

  1-(O-α-D-Glucopyranosyl)-3S,25R-hexacosanediol hexaacetate 在 硫酸 、 水 、 sodium carbonate 、 对甲苯磺酸 作用下， 以 甲醇 为溶剂， 反应 62.0h， 生成 (R)-23-((S)-2,2-Dimethyl-[1,3]dioxan-4-yl)-tricosan-2-ol
  参考文献：
  名称：

  Structure of the “heterocyst glycolipids” of the marine cyanobacterium Nodularia harveyana

  摘要：

  The ''heterocyst glycolipids'' have been reported to take part in the protection of the specialized cyanobacterial cells capable of N2 fixation against the penetration Of O2. For the first time such glycolipids have been isolated in a pure form from a cyanobacterium, Nodularia harveyana, and their structures have been established by spectroscopic and chemical means to be 1-(O-alpha-D-glucopyranosyl)-3R,25R-hexacosanediol, 1-(O-alpha-D-glucopyranosyl)-3S,25R-hexacosanediol and 1-(O-alpha-D-glucopyranosyl)-3-keto-25R-hexacosanol.

  DOI：

  10.1016/s0040-4020(01)89033-5