[(1,5-cyclooctadiene)PdMe(OPh)] | 541540-21-0

• 英文名称: [(1,5-cyclooctadiene)PdMe(OPh)]
• CAS: 541540-21-0
• 化学式: C₁₅H₂₀OPd
• 分子量: 322.743
• InChiKey: DCRSCIBKQIBIDC-PHFPKPIQSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [(1,5-cyclooctadiene)PdMe(OPh)] 、 水 以 水 为溶剂， 以36%的产率得到[(1,5-cyclooctadiene)PdMe(OH)]
  参考文献：
  名称：

  Cyclooctadienemethylpalladium complexes: synthesis, structures and reactivity

  摘要：

  Organometallic complexes of the type [(COD)PdMe(L)](n+) (COD = 1,5-cyclooctadiene; n = 0, L = Cl, OH, OMe, OEt, OiPr, OPh, OTol, OMes; n = 1, L = H2O, PPh3, pyridine or collidine; n = 2, L = N-methyl-pyrazinium) were prepared and spectro-scopically characterised. The crystal structure of [(COD)PdMe(Col)](SbF6) and EXAFS studies on selected samples reveal structural characteristics of these complexes. The complexes undergo fast ligand exchange reactions in solution giving rise to new mono or binuclear palladium complexes. Neutral complexes with oxo-ligands OR are highly reactive towards oxo-nucleophiles, including water. The hydroxo complex [(COD)PdMe(OH)] and its structurally characterised dimeric analogue [(mu-OH){(COD)PdMe}(2)](+) seem to play an important role in hydrolysis reactions. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)01231-8
• 作为产物：
  描述：

  [(1,5-cyclooctadiene)PdMe(THF)](SbF6) 、 lithium phenolate 以 四氢呋喃 为溶剂， 以56%的产率得到[(1,5-cyclooctadiene)PdMe(OPh)]
  参考文献：
  名称：

  Cyclooctadienemethylpalladium complexes: synthesis, structures and reactivity

  摘要：

  Organometallic complexes of the type [(COD)PdMe(L)](n+) (COD = 1,5-cyclooctadiene; n = 0, L = Cl, OH, OMe, OEt, OiPr, OPh, OTol, OMes; n = 1, L = H2O, PPh3, pyridine or collidine; n = 2, L = N-methyl-pyrazinium) were prepared and spectro-scopically characterised. The crystal structure of [(COD)PdMe(Col)](SbF6) and EXAFS studies on selected samples reveal structural characteristics of these complexes. The complexes undergo fast ligand exchange reactions in solution giving rise to new mono or binuclear palladium complexes. Neutral complexes with oxo-ligands OR are highly reactive towards oxo-nucleophiles, including water. The hydroxo complex [(COD)PdMe(OH)] and its structurally characterised dimeric analogue [(mu-OH){(COD)PdMe}(2)](+) seem to play an important role in hydrolysis reactions. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)01231-8