N,N-bis{[(2-hydroxyphenyl)methylene]amino}-2-butenedinitrilato(2-)cobalt(II) | 77690-49-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氢异喹啉
• 英文名称: N,N-bis{[(2-hydroxyphenyl)methylene]amino}-2-butenedinitrilato(2-)cobalt(II)
• CAS: 77690-49-4
• 化学式: C₁₈H₁₀CoN₄O₂
• 分子量: 373.296
• InChiKey: NOHCRJDWFFRLJC-CEPYMJGESA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2,3-bis(2-hydroxybenzylideneimino)-2,3-butenedinitrile 、 cobalt(II) diacetate tetrahydrate 以 乙醇 为溶剂， 以29.4%的产率得到N,N-bis{[(2-hydroxyphenyl)methylene]amino}-2-butenedinitrilato(2-)cobalt(II)
  参考文献：
  名称：

  Molecular tristability of CoII(salen)-based (salen = N,N’-ethylene-bis(salicylideniminato) compounds

  摘要：

  The magnetic behaviors of Co(II) complexes of N,N'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminato, N,N'-bis(3-chlorosalicylidene)-1,2-cyclohexanediaminato, N,N'-bis(3,5-dichlorosalicylidene)-1,2-cyclohexanediaminato, (3-nitrosalicylidene)-1,2-cyclohexanediaminato, N,N'-bis(3,5-dinitrosalicylidene)-1,2-cyclohexanediaminato, and N,N'-diaminomaleonitrilebis(salicylideniminato) were studied to identify the presence molecular tristability that is observed for the parent Co(II)salen (salen = ethylenebis(salicylideniminato)). N,N'-bis(3,5-dinitrosalicylidene)-1,2-cyclohexanediaminato(2-)cobalt(II) exhibited tristable behavior similar to Co(II)salen, and it is anticipated to have a dimeric structure.

  DOI：

  10.1016/j.jmmm.2019.165375