tribenzylindium(tert-butylhydrazine) | 884598-45-2

• 英文名称: tribenzylindium(tert-butylhydrazine)
• CAS: 884598-45-2
• 化学式: C₂₅H₃₃InN₂
• 分子量: 476.37
• InChiKey: BJTUXQTUYCCRLL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  叔丁基肼 、 甲苯 、 tri-tert-butylindium(III) 以 甲苯 为溶剂， 以13%的产率得到tribenzylindium(tert-butylhydrazine)
  参考文献：
  名称：

  Dimethylindium hydrazides [Me2In-NH-NHR]2 (R=CMe3, C6H5)

  摘要：

  Trimethylindium reacted with phenyl- and tert-butylhydrazine by the release of methane and the formation of the corresponding dimethylindium hydrazides (1 and 2, respectively). Both products form dimers and possess four-membered In2N2 heterocycles with two exocyclic N-N bonds in their molecular cores. Interestingly, one compound (1) crystallizes with centrosymmetric molecules in which the N-N bonds are located oil different sides of the In2N2 ring (C-2v), while both N-N bonds are on the same side in 2 (C-2h). In contrast, the reaction of tri(tert-butyl)indium with tert-butylhydrazine yielded a quite unexpected product. Partial decomposition occurred, and in a low yield the adduct of tribenzylindium with the unchanged tert-butylhydrazine was isolated. In a remarkable reaction, the trialkylindium derivative did not react with the relatively acidic hydrazine, but by the release of the corresponding alkane with the solvent toluene. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.12.014