2-Methyl-4,6-bis(n-butylamino)-s-triazine | 26234-34-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: 2-Methyl-4,6-bis(n-butylamino)-s-triazine
• 英文别名: N,N'-dibutyl-6-methyl-[1,3,5]triazine-2,4-diamine；2-N,4-N-dibutyl-6-methyl-1,3,5-triazine-2,4-diamine
• CAS: 26234-34-4
• 化学式: C₁₂H₂₃N₅
• 分子量: 237.348
• InChiKey: GPRRIAYTHVXFNY-UHFFFAOYSA-N

物化性质

• 沸点：
  396.8±25.0 °C(Predicted)
• 密度：
  1.062±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  17
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  62.7
• 氢给体数：
  2
• 氢受体数：
  5

文献信息

• EPOXY/ACID ANHYDRIDE COMPOSITION
  申请人：NISSAN CHEMICAL INDUSTRIES, LIMITED

  公开号：EP0834523A1

  公开（公告）日：1998-04-08

  (Object) It is to provide an epoxy/acid anhydride composition comprising an epoxy compound and an acid anhydride serving as a curing agent wherein a substituted triazine of a specific structure is employed as a curing accelerator to thereby impart a long pot life, a high storage stability and good working characteristics to the composition and cause no defect such as bubbling or cracking in the cured resin. (Constitution of the invention) An epoxy/acid anhydride composition characterized by containing, as a curing accelerator, a substituted triazine of the formula [] (wherein X is an amino group, C1-18 monoalkylamino group, di C1-18 alkylamino group, morpholino group, piperidino group, methyl group or phenyl group; R1 and R2 independently each represent C1-12 alkyl group, C1-12 hydroxyalkyl group, C4-8 cycloalkyl group, C5-9 cycloalkylmethyl group or C5-9 methylcycloalkyl group) in an epoxy/acid anhydride composition in which an epoxy compound and an acid anhydride-curing agent are contained, and an epoxy/acid anhydride resin composition prepared by thermosetting the epoxy/acid anhydride composition.

  目的 提供一种环氧/酸酐组合物，该组合物由环氧化合物和用作固化剂的酸酐组成，其中使用了特定结构的取代三嗪作为固化促进剂，从而使该组合物具有较长的固化寿命、较高的储存稳定性和良好的工作特性，并且不会导致固化树脂出现气泡或开裂等缺陷。 (本发明的结构） 一种环氧树脂/酸酐组合物，其特征在于含有式[]的取代三嗪作为固化促进剂。 (其中 X 是氨基、C1-18 单烷基氨基、二 C1-18 烷基氨基、吗啉基、哌啶基、甲基或苯基；R1 和 R2 各自独立地代表环氧化合物和酸酐固化剂的环氧/酸酐组合物中的 C1-12 烷基、C1-12 羟基烷基、C4-8 环烷基、C5-9 环烷基甲基或 C5-9 甲基环烷基），以及通过热固化该环氧/酸酐组合物制备的环氧/酸酐树脂组合物。
• METHODS FOR MODIFYING 1,3,5-TRIAZINE DERIVATIVES
  申请人：NISSAN CHEMICAL INDUSTRIES, LIMITED

  公开号：EP0882720A1

  公开（公告）日：1998-12-09

  A method for modifying 1,3,5-triazine derivatives characterized by reacting a 1,3,5-triazine derivative having at least one amino or monosubstituted amino group on any of the ring carbon atoms with an alcohol by heating in the presence of a metallic catalyst and hydrogen to thereby introduce an alkyl or alkenyl group into each amino or monosubstituted amino group; another method for modifying 1,3,5-triazine derivatives characterized by reacting a 1,3,5-triazine derivative having at least one amino or monosubstituted amino group on any of the ring carbon atoms with a dihydric alcohol by heating in the presence of a metallic catalyst and hydrogen to thereby introduce a hydroxylated alkyl group into each amino or monosubstituted amino group; and 1,3,5-triazine derivatives obtained by the methods. The various modified substituted 1,3,5-triazine derivatives thus produced are generally obtained as a mixture. These derivatives can be isolated as high-purity compounds by a general separation method for organic compounds, and the compounds are usable in the various applications mentioned in the specification. According to applications (for example, use as modifier additives, in particular a flame-retardant and a plasticizer for resins), the reaction mixture can be used as it is without being separated. Many of the substituted triazine derivatives obtained have been relatively difficult to synthesize or expensive. Since many of the derivatives are interesting with respect to their physical properties, e.g., solubility in water and in various organic solvents, high-temp. stability, melting point, boiling point, and basicity, they are thought to have a wider range of applications than conventional ones.

  一种改性 1，3，5-三嗪衍生物的方法，其特征在于在金属催化剂和氢的存在下，通过加热使任一环碳原子上具有至少一个氨基或单取代氨基的 1，3，5-三嗪衍生物与醇反应，从而在每个氨基或单取代氨基中引入一个烷基或烯基；另一种改性 1,3,5-三嗪衍生物的方法，其特征在于在金属催化剂和氢气存在下，使任一环碳原子上具有至少一个氨基或单取代氨基的 1,3,5-三嗪衍生物与二元醇反应，从而在每个氨基或单取代氨基中引入羟基烷基；以及通过上述方法获得的 1,3,5-三嗪衍生物。这样制得的各种改性取代的 1,3,5-三嗪衍生物通常以混合物的形式获得。这些衍生物可作为高纯度化合物通过有机化合物的一般分离方法分离出来，这些化合物可用于说明书中提到的各种应用中。根据用途（例如用作改性添加剂，特别是阻燃剂和树脂增塑剂），反应混合物可以不经分离直接使用。所获得的许多取代三嗪衍生物都比较难以合成或价格昂贵。由于许多衍生物在物理性质（如在水和各种有机溶剂中的溶解性、高温稳定性、熔点、沸点和碱性）方面都很有趣，因此它们被认为比传统的衍生物具有更广泛的用途。
• HUMIDITY DEPENDENCE IMPROVER FOR POLYMER FILM, POLYMER FILM, PROTECTIVE FILM FOR POLARIZER, RETARDATION FILM, POLARIZER, AND LIQUID CRYSTAL DISPLAY DEVICE
  申请人：Yasuda Takayasu

  公开号：US20110073007A1

  公开（公告）日：2011-03-31

  A humidity dependence improver for polymer film, comprising a compound of the following formula (1) or (2): wherein Ra, Rb and Rc represent an alkyl group, an alkenyl group, an alkynyl group, an aryl group or a heterocyclic group; X 1 to X 6 represent a single bond or a divalent linking group; R 1 to R 6 represent a hydrogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group or a heterocyclic group.
• US6124381A
  申请人：——

  公开号：US6124381A

  公开（公告）日：2000-09-26
• US6127538A
  申请人：——

  公开号：US6127538A

  公开（公告）日：2000-10-03