cis-Pt(EtNH2)2(PhCOO)2 | 306972-22-5

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 直链 1,3-二芳基丙烷
• 英文名称: cis-Pt(EtNH2)2(PhCOO)2
• CAS: 306972-22-5
• 化学式: C₁₈H₂₄N₂O₄Pt
• 分子量: 527.48
• InChiKey: VZVQKLXXWIMCGY-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  bis(ethylamino)platinum(IV) iodide 、 水 、 silver sulfate 、 barium benzoate 以 水 为溶剂， 生成 cis-Pt(EtNH2)2(PhCOO)2
  参考文献：
  名称：

  Synthesis and characterization of Pt(II) complexes with amine and carboxylato ligands. Crystal structure of (1,1-cyclobutanedicarboxylato)di(ethylamine)platinum(II)·H2O

  摘要：

  Two methods for the synthesis of compounds of the type cis-PtA(2)X(2) (A(2) = bidentate amine or two monodentate amines and X-2 = bidentate or two monodentate carboxylato ligands) were evaluated. The compounds were characterized by multinuclear NMR and IR spectroscopies. The Pt-195 NMR chemical shifts were in the range -1615 to -1976 ppm, the higher field values corresponding to the complexes containing bidentate ligands. The coupling constants (3)J(Pt-195-H-1) are approximately 35 Hz, while the (2)J(Pt-195-(HN)-H-1) are about 70 Hz. One coupling constant (2)J(Pt-195-C-13) (53 Hz) was also measured. The crystal structure of the compound, cis-Pt(1,1-cyclobutanedicarboxylato)(C2H5NH2)(2). H2O belongs to the P2(1)/n space group with a = 9.468(5), b = 9.365(4), c = 16.473(7) Angstrom, beta = 105.08(3)degrees, Z = 4 and R-1 = 0.0576. The Pt-N bond distances are 1.992(5) and 2.020(5) Angstrom, while the Pt-O bonds are 2.000(4) and 2.015(4) Angstrom. The molecules are held together by intermolecular H-bonds involving the lattice water molecules and the two free carbonyl O atoms and between the amino H atoms and the Pt-bonded C-O groups. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(00)00171-7