(Z)-1-bromo-1,2-dideuterio-ethene | 683-49-8

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 英文名称: (Z)-1-bromo-1,2-dideuterio-ethene
• 英文别名: (Z)-1-bromo-1,2-dideuterio-ethene；1-bromo-1,2-dideuterio-ethene；1-Brom-1,2-dideuterio-aethylen；1-Brom-1,2-dideuterio-aethen；1-Brom-aethylen-1.2-d₂；1-Brom-1.2-dideutero-aethylen；cis-1-Brom-1,2-dideuterio-ethylen
• CAS: 683-49-8
• 化学式: C₂H₃Br
• 分子量: 108.934
• InChiKey: INLLPKCGLOXCIV-ITQDIREFSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.52
• 重原子数：
  3.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  乙炔-1,2-D2 在 氢溴酸 作用下， 生成 (Z)-1-bromo-1,2-dideuterio-ethene
  参考文献：
  名称：

  Jungers; Verhulst, Memoires de la Classe des sciences. Academie royale de Belgique. Collection in 8, 1949, vol. 23, # 2, p. 36

  摘要：

  DOI：

文献信息

• Photochemistry of Hydrogen Bromide-Acetylene Complexes in Solid Krypton
  作者：Samuel A. Abrash、Celia M. Carr、Michael T. McMahon、Robert W. Zehner

  DOI：10.1021/j100097a017

  日期：1994.11

  Hydrogen-bonded complexes between HBr and acetylene in inert gas matrices were subjected to medium-pressure Hg lamp photolysis at 12 K. For HBr-acetylene, the major product was bromoacetylene, while vinyl bromide was present in trace amounts. When HBr-perdeuterioacetylene and DBr-acetylene complexes were photolyzed, bromoacetylene, deuteriobromoacetylene, and the hydrogen exchange product, DBr(HBr)-C2HD, were the primary products. Partially deuterated vinyl bromides were present in trace amounts. In HBr-perdeuterioacetylene, the only isomer observed was cis-CDBr=CHD. Ln DBr-acetylene, both cis- and trans-CHBr=CHD were observed, In neither experiment was the 1,1 addition product formed. The results are interpreted in terms of the supramolecule model of complex photochemistry put forth by Abrash and Pimentel.
• Jungers; Verhulst, Memoires de la Classe des sciences. Academie royale de Belgique. Collection in 8, 1949, vol. 23, # 2, p. 36,37
  作者：Jungers、Verhulst

  DOI：——

  日期：——