hydroxyoxo(5,10,15,20-tetraphenylporphinato)tungsten(V) | 58441-02-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: hydroxyoxo(5,10,15,20-tetraphenylporphinato)tungsten(V)
• 英文别名: tetraphenylporphyrinato W；O=W(OH)(TPP)；[OW(OH)(meso-tetraphenylporphine)]；[OW(OH)TPP]
• CAS: 58441-02-4
• 化学式: C₄₄H₂₉N₄O₂W
• 分子量: 829.59
• InChiKey: DUVUDLJEAZEAHK-NBICUONBSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  hydroxyoxo(5,10,15,20-tetraphenylporphinato)tungsten(V) 在 硫化氢 作用下， 以 甲苯 为溶剂， 生成
  参考文献：
  名称：

  Tipugina; Lomova; Ageeva, Russian Journal of General Chemistry, 1999, vol. 69, # 3, p. 441 - 445

  摘要：

  DOI：
• 作为产物：
  描述：

  [OW(OH)(Py)TPP] 以 甲苯 为溶剂， 生成 hydroxyoxo(5,10,15,20-tetraphenylporphinato)tungsten(V)
  参考文献：
  名称：

  Tipugina; Lomova, Russian Journal of Inorganic Chemistry, 2004, vol. 49, # 8, p. 1180 - 1184

  摘要：

  DOI：

文献信息

• Lomova, T. N.; Berezin, B. D., Russian Journal of Coordination Chemistry, 1993, vol. 19, p. 191 - 205
  作者：Lomova, T. N.、Berezin, B. D.

  DOI：——

  日期：——
• Hydroxyoxo(5,10,15,20-tetraphenylporphinato)tungsten(V) as a receptor for foodstuff and drug components. Thermodynamics of supramolecular complexation
  作者：E. V. Motorina、T. N. Lomova

  DOI：10.1134/s0036023610050116

  日期：2010.5

  The thermodynamics of stepwise reactions of hydroxyoxo(5,10,15,20-tetraphenylporphinato)tungsten(V) (O=W(OH)TPP) with biologically active base molecules was studied. For the reaction of O=W(OH)TPP with benzimidazole, four steps were found and studied; the equilibrium constants K (n) were determined to be 2.55 x 10(4), 1.87 x 10(3) L/mol, 1.06 x 10(6), 4.09 x 10(4) L-2/mol(2). The reaction of O=W(OH)TPP with pyrazine was a one-step reversible process of Pyz coordination to the eighth coordination site (K = 399 L/mol). The correlation equations relating the stability of supramolecular complexes to pK of the bases were obtained. The thermodynamic data were used to demonstrate the prospects of applying the metal porphyrin as a receptor for N-bases in membranes, sensors, and analytical devices for quality control of foodstuffs, drugs, and gas mixtures for the content of VOCs.
• Lomova, T. N.; Volkova, N. I.; Berezin, B. D., Russian Journal of Inorganic Chemistry, 1985, vol. 30, p. 352 - 354
  作者：Lomova, T. N.、Volkova, N. I.、Berezin, B. D.

  DOI：——

  日期：——