[Pd(CH3)(1,2-bis(diphenylphosphinomethyl)benzene)(CH3CN)](trifluoromethane sulfonate) | 913729-23-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磺酸及其衍生物
• 英文名称: [Pd(CH3)(1,2-bis(diphenylphosphinomethyl)benzene)(CH3CN)](trifluoromethane sulfonate)
• CAS: 913729-23-4
• 化学式: CF₃O₃S*C₃₅H₃₄NP₂Pd
• 分子量: 786.1
• InChiKey: OYLQYDWWVAQOOG-UHFFFAOYSA-M

反应信息

• 作为反应物：
  描述：

  [Pd(CH3)(1,2-bis(diphenylphosphinomethyl)benzene)(CH3CN)](trifluoromethane sulfonate) 、 一氧化碳 以 氘代氯仿 为溶剂， 生成 [Pd(C(O)CH3)(1,2-bis(diphenylphosphinomethyl)benzene)(CH3CN)](trifluoromethane sulfonate)
  参考文献：
  名称：

  High-pressure NMR study of migratory CO-insertion in palladium–methyl complexes modified with Cs-symmetrical 1,4-diphosphines

  摘要：

  Carbonylation of the palladium complexes [PdCH3((PP)-P-boolean AND')Cl] ((PP)-P-boolean AND'= 1a, 1b, 1c, 1d, 1e) and [PdCH3((PP)-P-boolean AND')(CH3CN)](OTf) was investigated by means of high-pressure NMR with the determination of the half-life times t(1/2). The results were rationalized on the basis of the electronic properties of the diphosphines and the nature of the solvento ligand in the first coordination sphere. The crystal structures of the complexes [Pd(1b)Cl-2] and [Pd(1b)(H2O)(2)](OTf)(2) are described (1b = 1-(diphenylphosphinomethyl)-2-[bis(3- trifluoromethylphenyl)phosphinomethyl]benzene). (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.01.020

文献信息

• Olefin insertion in Pd-acyl complexes modified with 1,4-Cs-symmetrical diphosphine ligands
  作者：Antonella Leone、Giambattista Consiglio

  DOI：10.1016/j.jorganchem.2006.06.029

  日期：2006.10

  The insertion of ethene and propene was investigated in palladium(II) acyl complexes of the type [PdC(O)CH3(P∧P′)(CH3CN)](OTf) modified with the Cs-symmetric diphosphines 2–4 and the parent ligand 1, described by C2v-symmetry and taken as a reference.

  乙烯和丙烯的插入在钯进行了研究（II）的酰基类型的配合物[PDC（O）CH 3（P ∧ P'）（CH 3 CN）]（OTF）与改性Ç小号-对称二膦2 -参照图4，通过C 2 v-对称性进行说明，并作为参照，参照母体配体1。