2-Amino-1,1-bis-(2-butoxy-5-tert-butyl-phenyl)-3-phenyl-propan-1-ol | 54464-61-8

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 直链 1,3-二芳基丙烷
• 英文名称: 2-Amino-1,1-bis-(2-butoxy-5-tert-butyl-phenyl)-3-phenyl-propan-1-ol
• 英文别名: 2-Amino-1,1-bis(2-butoxy-5-tert-butylphenyl)-3-phenylpropan-1-ol
• CAS: 54464-61-8
• 化学式: C₃₇H₅₃NO₃
• 分子量: 559.833
• InChiKey: VFOWVXGKEFNVCK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.4
• 重原子数：
  41
• 可旋转键数：
  15
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.51
• 拓扑面积：
  64.7
• 氢给体数：
  2
• 氢受体数：
  4

文献信息

• Chiral copper complex catalyst composition and asymmetric production process using the same
  申请人：——

  公开号：US20010037036A1

  公开（公告）日：2001-11-01

  There is disclosed chiral copper complex catalyst composition, which is obtained by contacting an optically active N-salicylideneaminoalcohol compound of formula (1): 1 with a mono-valent or di-valent copper compound in an inert solvent, wherein R 1 and R 2 represent an alkyl group and the like, X 1 and X 2 represent a hydrogen atom, a halogen atom, a nitro group, an alkyl group, an alkoxy group, a cyano group or the like, and the amount of the mono-valent or di-valent copper compound is less than 1 mole per 1 mole of the optically active N-salicylideneaminoalcohol compound of formula (1), and a process for producing an optically active cylopropane-carboxylic acid ester using the same.

  披露了手性铜配合物催化剂组合物，该组合物是通过将式（1）中的光学活性N-水杨醛亚氨基醇化合物与一价或二价铜化合物在惰性溶剂中接触而获得的，其中R1和R2代表烷基基团等，X1和X2代表氢原子、卤素原子、硝基团、烷基基团、烷氧基团、氰基团等，一价或二价铜化合物的量小于1摩尔与式（1）中的光学活性N-水杨醛亚氨基醇化合物的摩尔比，以及使用该组合物生产光学活性环丙烷羧酸酯的方法。
• Chiral copper complex and production processes thereof and using the same
  申请人：Kamitamari Masashi

  公开号：US20050090684A1

  公开（公告）日：2005-04-28

  There is disclosed an optically active salicylideneaminoalcohol compound of formula (1): wherein R 1 represents an alkyl group or the like, R 2 represents an aryl group and the like, and when X 1 represents a nitro, X 2 is a hydrogen atom, when X 1 represents a chlorine atom, X 2 is a chlorine atom, and when X 1 is a hydrogen atom, X 2 is a fluorine atom; and the carbon atom denoted by “*” is an asymmetric carbon atom having either an S or R configuration, and a chiral copper complex produced from the optically active salicylidenaminoalcohol compound and a copper compound.

  公开了一种光学活性的萨利基利丙氨醇化合物，其化学式为(1)：其中，R1代表烷基或类似物，R2代表芳基或类似物，当X1代表硝基时，X2是氢原子，当X1代表氯原子时，X2是氯原子，当X1是氢原子时，X2是氟原子；而由光学活性萨利基利丙氨醇化合物和铜化合物制备的手性铜络合物中，用“*”表示的碳原子是具有S或R构型的不对称碳原子。
• US6469198B2
  申请人：——

  公开号：US6469198B2

  公开（公告）日：2002-10-22
• US6670500B2
  申请人：——

  公开号：US6670500B2

  公开（公告）日：2003-12-30
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  申请人：——

  公开号：US7009079B2

  公开（公告）日：2006-03-07