1,4-Butylene glycol diadipate | 53212-17-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 1,4-Butylene glycol diadipate
• 英文别名: 6-[4-(5-carboxypentanoyloxy)butoxy]-6-oxohexanoic acid
• CAS: 53212-17-2
• 化学式: C₁₆H₂₆O₈
• 分子量: 346.378
• InChiKey: LERHUIIYMDMWNC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1
• 重原子数：
  24
• 可旋转键数：
  17
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  127
• 氢给体数：
  2
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  1,4-Butylene glycol diadipate 生成
  参考文献：
  名称：

  利用可再生生物资源，即。山梨糖醇，二醇和二酸，用于制备两包PU防腐涂料†

  摘要：

  本研究工作揭示了使用可再生成分来合成聚氨酯的聚酯多元醇部分，这是一种不同于传统方式的改性方法，方法是通过熔体冷凝技术。根据链长和分子量选择用于制备聚酯多元醇的双官能酸。可再生和不可再生的双官能酸都用于比较每种配方的涂层性能。还针对可持久生产2K PU涂层的结构参数，针对其对最终涂层性能的影响，研究了耐化学腐蚀性能。合成涂料的特征还在于光泽度，附着力，柔韧性和铅笔硬度等技术。总体而言，发现基于癸二酸的配方最适合用于涂层性能，尤其是防腐性能，光泽度和铅笔硬度。

  DOI：

  10.1039/c5ra17202k
• 作为产物：
  描述：

  己二酸 、 1,4-丁二醇 在 对甲苯磺酸 作用下， 生成 1,4-Butylene glycol diadipate
  参考文献：
  名称：

  利用可再生生物资源，即。山梨糖醇，二醇和二酸，用于制备两包PU防腐涂料†

  摘要：

  本研究工作揭示了使用可再生成分来合成聚氨酯的聚酯多元醇部分，这是一种不同于传统方式的改性方法，方法是通过熔体冷凝技术。根据链长和分子量选择用于制备聚酯多元醇的双官能酸。可再生和不可再生的双官能酸都用于比较每种配方的涂层性能。还针对可持久生产2K PU涂层的结构参数，针对其对最终涂层性能的影响，研究了耐化学腐蚀性能。合成涂料的特征还在于光泽度，附着力，柔韧性和铅笔硬度等技术。总体而言，发现基于癸二酸的配方最适合用于涂层性能，尤其是防腐性能，光泽度和铅笔硬度。

  DOI：

  10.1039/c5ra17202k

文献信息

• Resin composition and molded object formed from the resin composition
  申请人：Tanaka Kazuya

  公开号：US20060148969A1

  公开（公告）日：2006-07-06

  Disclosed is a resin composition that has excellent impact resistance and excellent heat resistance without substantially deteriorating biodegradability that the lactic acid based resin has inherently. The resin composition includes (A) a lactic acid based resin; (B) an aromatic aliphatic polyester having a glass transition temperature (Tg) of 0° C. or less and a heat of crystal melting (AHm) of 5 J/g to 30 J/g, and/or an aliphatic polyester other than the lactic acid based resin, having a glass transition temperature (Tg) of 0° C. or less and a heat of crystal melting (ΔHm) of 5 J/g to 30 J/g, and (B) an aromatic aliphatic polyester having a glass transition temperature (Tg) of 0° C. or less and a heat of crystal melting (ΔHm) of 5 J/g to 30 J/g, and/or an aliphatic polyester other than the lactic acid based resin, having a glass transition temperature (Tg) of 0C or less and a heat of crystal melting (ΔHm) of 5 J/g to 30 J/g, has a content of 5 mass % to 25 mass %.

  揭示了一种具有出色的抗冲击性和出色的耐热性的树脂组合物，而不会实质性地降低乳酸基树脂固有的生物降解性。该树脂组合物包括(A) 乳酸基树脂；(B) 具有0°C或更低玻璃转变温度（Tg）和5 J/g至30 J/g结晶熔化热（ΔHm）的芳香族脂肪族聚酯，和/或除乳酸基树脂外的脂肪族聚酯，具有0°C或更低的玻璃转变温度（Tg）和5 J/g至30 J/g结晶熔化热（ΔHm）；(B) 具有0°C或更低的玻璃转变温度（Tg）和5 J/g至30 J/g结晶熔化热（ΔHm）的芳香族脂肪族聚酯，和/或除乳酸基树脂外的脂肪族聚酯，具有0°C或更低的玻璃转变温度（Tg）和5 J/g至30 J/g结晶熔化热（ΔHm），其含量为5质量%至25质量%。
• CATIONIC DYEABLE POLYURETHANE ELASTIC YARN AND METHOD OF PRODUCTION
  申请人：Tanaka Toshihiro

  公开号：US20100130083A1

  公开（公告）日：2010-05-27

  Disclosed is a polyurethane elastic yarn which is excellent in elongation, resilience, heat resistance, alkali resistance, chemical resistance, and capability of being dyed with a cationic dye and which is suitable for use in a stretch cloth, a wearing apparel or the like. The polyurethane elastic yarn comprises: an elastic yarn comprising a polyurethane mainly composed of a polymer diol and a diisocyanate; and a polymer of a compound having a sulfonate group contained in the elastic yarn.

  本发明涉及一种聚氨酯弹性纱线，其具有良好的延展性、弹性、耐热性、耐碱性、耐化学性和阳离子染料染色能力，并适用于伸展布料、服装等用途。该聚氨酯弹性纱线包括：一种弹性纱线，其包括主要由聚合物二元醇和二异氰酸酯组成的聚氨酯；以及包含有磺酸基团化合物的聚合物，其含于所述弹性纱线中。
• Rosin-Derived Cationic Compounds and Polymers Along with Their Methods of Preparation
  申请人：Tang Chuanbing

  公开号：US20120214950A1

  公开（公告）日：2012-08-23

  Methods for forming rosin-derived cationic compounds are provided. The method can include attaching a cationic group to a conjugated diene on a hydrophenathrene-based ring of a resin acid (e.g., levopimaric acid, abietic acid, dehydroabietic acid, or a mixture thereof) to form a rosin-derived cationic compound. Attaching the cationic group to the conjugated diene on the hydrophenathrene-based ring of the resin acid can be achieved via a Diels-Alder reaction of a dienophile with the hydrophenathrene-based ring of the resin acid. Rosin-derived cationic compounds are also provided. The rosin-derived cationic compound can include a cationic group attached to a conjugated diene on a hydrophenathrene-based ring of a resin acid, wherein the rosin-derived cationic compound further comprises a carboxylic acid group.

  提供了制备松香衍生阳离子化合物的方法。该方法可以包括将阳离子基团连接到树脂酸（例如左旋松香酸、松香酸、脱氢松香酸或其混合物）的一个基于羟基苯并环的环上的共轭二烯上，以形成松香衍生阳离子化合物。通过将阳离子基团连接到树脂酸基于羟基苯并环的环上的共轭二烯，可以通过二烯丙烯与树脂酸基于羟基苯并环的环的Diels-Alder反应来实现。还提供了松香衍生阳离子化合物。该松香衍生阳离子化合物可以包括连接到树脂酸基于羟基苯并环的环上的共轭二烯上的阳离子基团，其中该松香衍生阳离子化合物还包括一个羧酸基团。
• PROCESSING AID COMPOSITION DERIVED FROM A SULFINATE-CONTAINING MOLECULE
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US20140378594A1

  公开（公告）日：2014-12-25

  Described herein is a melt-processible polymer composition comprising: a non-fluorinated melt-processible polymer; and a fluoropolymer derived from the polymerization of a monomer and a sulfinate-containing molecule, wherein the sulfinate-containing molecule is selected from the group consisting of: (a) CX 1 X 3 ═CX 2 —(R) p —CZ 1 Z 2 —SO 2 M Formula (I) (b) Formula (II); and (c) combinations thereof, wherein X 1 , X 2 , and X 3 are each independently selected from H, F, Cl, a C 1 to C 4 alkyl group, and a C 1 to C 4 fluorinated alkyl group; R is a linking group; Z 1 and Z 2 are independently selected from F, CF 3 , and a perfluoroalkyl group; R 1 and R 2 are end-groups; p is 0 or 1; m is at least 2; and M is a cation.

  本文描述了一种可熔处理的聚合物组合物，包括：一种非氟可熔处理聚合物；以及由单体和含有磺酸盐分子聚合而成的氟聚合物，其中所述的磺酸盐分子选自以下组：（a）CX1X3═CX2—（R）p—CZ1Z2—SO2M式（I）；（b）式（II）；和（c）其组合物，其中X1、X2和X3各自独立选择自H、F、Cl、C1到C4烷基和C1到C4氟烷基；R是连结基；Z1和Z2各自独立选择自F、CF3和全氟烷基；R1和R2是末端基；p为0或1；m至少为2；M是阳离子。
• Rosin-Derived Cationic Compounds and Polymers
  申请人：Tang Chuanbing

  公开号：US20140163174A1

  公开（公告）日：2014-06-12

  Methods for forming rosin-derived cationic compounds are provided. The method can include attaching a cationic group to a conjugated diene on a hydrophenathrene-based ring of a resin acid (e.g., levopimaric acid, abietic acid, dehydroabietic acid, or a mixture thereof) to form a rosin-derived cationic compound. Attaching the cationic group to the conjugated diene on the hydrophenathrene-based ring of the resin acid can be achieved via a Diels-Alder reaction of a dienophile with the hydrophenathrene-based ring of the resin acid. Rosin-derived cationic compounds are also provided. The rosin-derived cationic compound can include a cationic group attached to a conjugated diene on a hydrophenathrene-based ring of a resin acid, wherein the rosin-derived cationic compound further comprises a carboxylic acid group.

  提供了制备松香衍生阳离子化合物的方法。该方法可以包括将阳离子基团连接到树脂酸（例如左旋松香酸、松香酸、脱氢松香酸或其混合物）的羟基苯并[3.3.1]环上的共轭二烯上，形成松香衍生阳离子化合物。通过二烯丙烯与树脂酸的羟基苯并[3.3.1]环进行Diels-Alder反应，可以将阳离子基团连接到树脂酸的羟基苯并[3.3.1]环上。还提供了松香衍生阳离子化合物。该松香衍生阳离子化合物可以包括连接到树脂酸的羟基苯并[3.3.1]环上的共轭二烯上的阳离子基团，其中该松香衍生阳离子化合物进一步包括一个羧酸基团。