青霉胺杂质 | 884311-05-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 青霉胺杂质
• 英文名称: N-formyl-L-penicillamine
• 英文别名: N-Formyl-L-penicillamin；N-Formyl-penicillamin；N-formylpenicillamin；(2R)-2-formamido-3-methyl-3-sulfanylbutanoic acid
• CAS: 884311-05-1
• 化学式: C₆H₁₁NO₃S
• 分子量: 177.224
• InChiKey: ANCLDHSEMKEXLS-SCSAIBSYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.1
• 重原子数：
  11
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  67.4
• 氢给体数：
  3
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  青霉胺杂质 在 盐酸 作用下， 生成 L-青霉胺
  参考文献：
  名称：

  Wilson; du Vigneaud, Journal of Biological Chemistry, 1950, vol. 184, p. 63,68

  摘要：

  DOI：
• 作为产物：
  描述：

  S-benzyl-N-formyl-L-penicillamine 在 氨 、 sodium 作用下， 生成 青霉胺杂质
  参考文献：
  名称：

  Wilson; du Vigneaud, Journal of Biological Chemistry, 1950, vol. 184, p. 63,68

  摘要：

  DOI：

文献信息

• Effect of Mn cluster on the formation of Superoxide radicals in photoinhibition of photosystem II
  作者：Suping Zhang、Tiecheng Tu、Jun Weng、Jingxi Pan、Chunhe Xu、Side Yao

  DOI：10.1007/bf02901162

  日期：2001.11

  To further realize the action of superoxide radicals (O-2(-.)) in photoinhibition of photosystem II (PS II), we employed 5,5-dimethyl-1-pyrroline-N-oxide (DMPO) as a spin trap, associated with EPR spectroscopy, to study the effect of illumination time on O-2(-.) formation during high light photoinhibition in PS II membranes and Mn-depleted PS II membranes. Results indicated that the removal of Mn cluster from PS II membranes has a strong influence on the dynamics of superoxide formation. The relative mechanism was also discussed. These novel findings may further promote the studies of the structure and function of PS II and the mechanism of photoinhibition.
• Crooks, Chemistry of Penicillin
  作者：Crooks

  DOI：——

  日期：——
• FUJII, TADAO;MIZUSHIMA, NORIKO;KUBOTA, AKIE;OHUCHI, FUMINOBU;MACHIDA, YOS+, YAKUDZAJGAKU, 48,(1988) N, S. 181-188
  作者：FUJII, TADAO、MIZUSHIMA, NORIKO、KUBOTA, AKIE、OHUCHI, FUMINOBU、MACHIDA, YOS+

  DOI：——

  日期：——
• INK COMPOSITION FOR INKJET RECORDING, INK CARTRIDGE INCLUDING THE INK COMPOSITION, AND INKJET RECORDING APPARATUS INCLUDING THE INK CARTRIDGE
  申请人：Park Hyo-keun

  公开号：US20090000510A1

  公开（公告）日：2009-01-01

  An ink composition is provided for inkjet recording including a compound represented by Formula 1, a coloring agent, and water, the ink composition having characteristics that prevent formation of depositions therein over time to obtain high storage stability and good ejection properties. wherein R 1 and R 2 are each independently, hydrogen, a substituted or unsubstituted C 1 -C 20 alkyl group, a substituted or unsubstituted C 2 -C 20 alkenyl group, a substituted or unsubstituted C 2 -C 20 alkynyl group, a substituted or unsubstituted C 6 -C 20 aryl group, a substituted or unsubstituted C 7 -C 20 arylalkyl group, a substituted or unsubstituted C 3 -C 20 cyclic alkyl group, or a substituted or unsubstituted C 2 -C 20 hetero atom-containing cyclic alkyl group, R 3 is hydrogen, a formyl group or an acetyl group, and M is hydrogen, Na, K, Li, an ammonium ion or an anilinium ion.
• US7527682B2
  申请人：——

  公开号：US7527682B2

  公开（公告）日：2009-05-05