[Zn(2,2',2''-[1,3,5-triazine-2,4,6-triyltris(thio)]aceticacid-diacetate)(2,2'-bipyridine)(H2O)3] | 1315563-91-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: [Zn(2,2',2''-[1,3,5-triazine-2,4,6-triyltris(thio)]aceticacid-diacetate)(2,2'-bipyridine)(H2O)3]
• CAS: 1315563-91-7
• 化学式: C₁₉H₂₁N₅O₉S₃Zn
• 分子量: 624.992
• InChiKey: RNHSTDVFHZYELD-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  水 、 zinc(II) acetate dihydrate 、 2,2'-联吡啶 、 2,2′,2″-[1,3,5-triazine-2,4,6-triyltris(thio)]tris-acetic acid 以 水 为溶剂， 生成 [Zn2(2,2',2''-[1,3,5-triazine-2,4,6-triyltris(thio)]acetic acid-diacetate)2(2,2'-bipyridine)2(H2O)2] 、 [Zn(2,2',2''-[1,3,5-triazine-2,4,6-triyltris(thio)]aceticacid-diacetate)(2,2'-bipyridine)(H2O)3]
  参考文献：
  名称：

  pH- and metal-dependent structural diversity from mononuclear to two-dimensional polymers based on a flexible tricarboxylate ligand

  摘要：

  Six complexes based on a flexible tripodal ligand H(3)TTTA (2,2',2 ''-[1,3,5-triazine-2,4,6-triyltris(thio)]-tris-acetic acid) have been hydrothermally synthesized and structurally characterized. X-ray single-crystal diffractions reveal that they have rich structural chemistry: mononuclear, [Zn(HTTTA)(2,2'-bPy)(H2O)(3)](n) (1); dimeric metallamacrocycle, [Zn(HTTTA)(2,2'-bipy)(H2O)](n) (2) and [Cd(HTTTA)(2,2'-bipy)(H2O)center dot H2O](n) (3); two-dimensional networks with binodal (3,6)-connected Cdl(2) topology based on linear trinuclear M-3(mu(2)-CO2)(4)(mu(2)-CO2)(2) SBUs (Secondary Building Units), [M-3(TTTA)(2)(2,2'-bipy)(2)(H2O)(m)center dot nH(2)O](n) (M=Zn.4, m=0, n=4; Cd.5 and Mn.6, m=2; n=2). The value of pH and the metal ions has large influences on the resulting structures. The flexible tricarboxylic acid exhibits four coordination modes from monodentate to mu(6)-bridge. Fluorescence and magnetic properties of the complexes have also been investigated in details. (C) 2011 Elsevier Inc. All rights reserved.

  DOI：

  10.1016/j.jssc.2011.04.029