tert-Butylperoxy-4-tert-butylazo-4-cyano-valerat | 24019-54-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: tert-Butylperoxy-4-tert-butylazo-4-cyano-valerat
• 英文别名: tert-butyl 4-(tert-butylazo)-4-cyanoperoxypentanoate；t-Butyl 4-(t-butylazo)-4-cyanoperoxypentanoate；tert-butyl 4-(tert-butyldiazenyl)-4-cyanopentaneperoxoate
• CAS: 24019-54-3
• 化学式: C₁₄H₂₅N₃O₃
• 分子量: 283.371
• InChiKey: FTTMWZNUYVDTCX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  20
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  84
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  4-氰基-4-[(1,1-二甲基乙基)偶氮]戊酸 以 四氢呋喃 为溶剂， 反应 6.5h， 生成 tert-Butylperoxy-4-tert-butylazo-4-cyano-valerat
  参考文献：
  名称：

  Synthesis and thermal properties of asymmetrical azo-peresters

  摘要：

  New asymmetrical azo-perester derivatives of tert-butyl and tert-amyl hydroperoxides were obtained by reacting azo acids with hydroperoxides in the presence of N,N'-carbonyldiimidazole. The obtained azo-peresters possess two labile functional groups: the azo group and the perester group. Data from dynamic differential scanning calorimetry (DSC) experiments indicate that the azo groups decompose at somewhat lower temperatures than the perester groups.

  DOI：

  10.1007/s00706-011-0459-9

文献信息

• Synthesis and thermal properties of asymmetrical azo-peresters
  作者：Barbara Hefczyc、Jan Zawadiak、Henryk Janeczek、Marek Kowalczuk、Beata Orlińska

  DOI：10.1007/s00706-011-0459-9

  日期：2011.3

  New asymmetrical azo-perester derivatives of tert-butyl and tert-amyl hydroperoxides were obtained by reacting azo acids with hydroperoxides in the presence of N,N'-carbonyldiimidazole. The obtained azo-peresters possess two labile functional groups: the azo group and the perester group. Data from dynamic differential scanning calorimetry (DSC) experiments indicate that the azo groups decompose at somewhat lower temperatures than the perester groups.