3,3'-((3-chlorophenyl)methylene)bis(2-phenyl-1H-indole) | 1218780-12-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 3,3'-((3-chlorophenyl)methylene)bis(2-phenyl-1H-indole)
• CAS: 1218780-12-1
• 化学式: C₃₅H₂₅ClN₂
• 分子量: 509.05
• InChiKey: ULQZAJQHYCDBJX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.82
• 重原子数：
  38.0
• 可旋转键数：
  5.0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.03
• 拓扑面积：
  31.58
• 氢给体数：
  2.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  2-苯基吲哚 、 3-氯苯甲醛 在 sulfated zirconia nanoparticles dispersed in poly(N-vinylpyrrolidone) 作用下， 以 neat (no solvent) 为溶剂， 反应 24.0h， 以90%的产率得到3,3'-((3-chlorophenyl)methylene)bis(2-phenyl-1H-indole)
  参考文献：
  名称：

  Well-dispersed sulfated zirconia nanoparticles as high-efficiency catalysts for the synthesis of bis(indolyl)methanes and biodiesel

  摘要：

  Well-dispersed sulfated zirconia nanoparticles were synthesized with poly(N-vinylpyrrolidone) as a surfactant. The resultant sulfated zirconia nanoparticles are characterized by SEM, XRD, FT-IR and XPS. These nanoparticles were directly used as catalysts for the synthesis of bis(indolyl)methanes and biodiesel via electrophilic substitution reaction of indole with various aldehydes and the esterification of long-chain free fatty acids and exhibited excellent catalytic activity. The mechanism of the formation of the synthesized zirconia nanoparticles was also proposed. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.catcom.2013.07.006

文献信息

• Kumar, B. Sunil; Hunnur, Raveendra K.; Reddy, K. Mallikarjun, Heterocyclic Communications, 2009, vol. 15, # 2, p. 115 - 120
  作者：Kumar, B. Sunil、Hunnur, Raveendra K.、Reddy, K. Mallikarjun、Udupi、Bindu, V. Hima

  DOI：——

  日期：——